(5beta)-3-氧代-胆烷-24-酸合成路线 （共 11 条）
反应条件
hydrogenchloride; lithium tri(t-butoxy)aluminum hydride in tetrahydrofuran; water
参考文献
Reindel; Niederlaender
Chemische Berichte, 1935 , vol. 68, p. 1243,1245
反应条件
jones' reagent in acetone
T=4°C; 0.5 h;
参考文献
Nahar, Lutfun; Turner, Alan B.
Journal of Chemical Research, 2004 , # 5 p. 329 - 332
反应条件
potassium hydroxide; hydrogen; acetic acid; palladium in ethanol; water
参考文献
Faarup, Peter
Patent: US2002/183531 A1, 2002 ;
→
668-49-54-(3,6-二羟基-10,13-二甲基-2,3,4,5,6,7,8,9,11,12,14,15,16,17-十四氢-1H-环戊并[a]菲-17-基)戊酸+
反应条件
pyridine; phosphate buffer; iodosylbenzene; catalyst in methanol; water; dimethyl sulfoxide
T=20°C; pH=10; Further byproducts.;
参考文献
Yang, Jerry; Gabriele, Bartolo; Belvedere, Sandro; Huang, Ying; Breslow, Ronald
The Journal of organic chemistry, 2002 , vol. 67, # 15 p. 5057 - 5067
反应条件
hydrogenchloride; acetic acid
参考文献
Kagan; Jacques
Bulletin de la Societe Chimique de France, 1957 , p. 699,703
反应条件
1: bromine; aqueous NaHCO3
2: dioxane; toluene-4-sulfonic acid
3: hydrazine hydrate; sodium hydroxide; diethylene glycol / 195 °C
4: aqueous HCl; acetic acid
View Scheme
参考文献
Kagan; Jacques
Bulletin de la Societe Chimique de France, 1957 , p. 699,703
反应条件
1: dioxane; toluene-4-sulfonic acid
2: hydrazine hydrate; sodium hydroxide; diethylene glycol / 195 °C
3: aqueous HCl; acetic acid
View Scheme
参考文献
Kagan; Jacques
Bulletin de la Societe Chimique de France, 1957 , p. 699,703
反应条件
1: dioxane; toluene-4-sulfonic acid
2: aq. NaOH solution
3: hydrazine hydrate; sodium hydroxide; diethylene glycol / 195 °C
4: aqueous HCl; acetic acid
View Scheme
参考文献
Kagan; Jacques
Bulletin de la Societe Chimique de France, 1957 , p. 699,703
反应条件
1: hydrazine hydrate; sodium hydroxide; diethylene glycol / 195 °C
2: aqueous HCl; acetic acid
View Scheme
参考文献
Kagan; Jacques
Bulletin de la Societe Chimique de France, 1957 , p. 699,703
反应条件
1: aq. NaOH solution
2: hydrazine hydrate; sodium hydroxide; diethylene glycol / 195 °C
3: aqueous HCl; acetic acid
View Scheme
参考文献
Kagan; Jacques
Bulletin de la Societe Chimique de France, 1957 , p. 699,703
