反应条件
<b>Multi-step reaction with 8 steps<br /> </b>1: 90 percent / TiCl<sub>4</sub> / CH<sub>2</sub>Cl<sub>2</sub> / 3 h / Ambient temperature<br />2: 1.) NH<sub>2</sub>NH<sub>2</sub>*H<sub>2</sub>O, 2.) KOH / 1.) toluene, diethylene glycol, reflux, 1 h, 2.) 180 deg C, 3 h<br />3: 80 percent / AlCl<sub>3</sub> / CH<sub>2</sub>Cl<sub>2</sub> / 2 h / Ambient temperature<br />4: 82 percent / TiCl<sub>4</sub> / CH<sub>2</sub>Cl<sub>2</sub> / 2 h / Ambient temperature<br />5: 1.) NH<sub>2</sub>NH<sub>2</sub>*H<sub>2</sub>O, 2.) KOH / 1.) toluene, diethylene glycol, reflux, 1 h, 2.) 180 deg C, 3 h<br />6: 70 percent / NBS, V-65 / benzene / 2 h / Irradiation<br />7: 38 percent / KOH, NaBH<sub>4</sub> / benzene; ethanol / 6 h<br />8: MCPBA / CHCl<sub>3</sub> / 6 h / -5 °C<br /> <br />
参考文献
Yamato, Takehiko; Miyazawa, Akira; Tashiro, Masashi Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1993 , # 24 p. 3127 - 3138
