sulfuric acid in water
Kinetics; byproducts: S2O6(2-); react. in continuous-flow stirred tank reactor, input soln. KBrO3 and Na2SO3 (+H2SO4); not isolated, measured pH oscillations;
参考文献
Szanto, Tibor G.; Rabai, Gyula
Journal of Physical Chemistry A, 2005 , vol. 109, # 24 p. 5398 - 5402
hydrogen cation in water
Kinetics; byproducts: Br(1-); oxidation of SCN(1-) by BrO3(1-) in acidic soln.; various conditions; mechanism discussed;;
参考文献
Radhakrishnamurti, P. S.; Misra, S. A.; Panda, J. K.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1981 , vol. 20, # 5 p. 459 - 461
perchloric acid in water
Kinetics; oscillatory reaction; flow experiments (continously stirred tank reactor or batch react., 25+/-0.1°C, excess of BrO3(1-);; not isolated, followed by redox potential or absorption measurements;;
参考文献
Simoyi, Reuben H.
Journal of Physical Chemistry, 1987 , vol. 91, # 6 p. 1557 - 1561
perchloric acid in water
Kinetics; oscillatory react.; flow experiments (continously stirred tank reactor or batch react., 25+/-0.1°C, equimolar concn. of BrO3(1-), SCN(1-); not isolated, followed by redox potential or absorption measurements;
参考文献
Simoyi, Reuben H.
Journal of Physical Chemistry, 1987 , vol. 91, # 6 p. 1557 - 1561
