5-甲基-3-硝基-4-氧代-1,4-二氢-2-吡啶羧酸合成路线 (共 6 条)
反应条件
hydrogen bromide
T=80 - 82°C; 4 h;
参考文献
Chu, Wenhua; Kamitori, Shigehiro; Shinomiya, Miho; Carlson, Robert G.; Takusagawa, Fusao
Journal of the American Chemical Society, 1994 , vol. 116, # 6 p. 2243 - 2253
反应条件
1: 90percent HNO3, 98percent H2SO4 / 4 h / 90 °C
2: 78 percent / acetyl chloride / 0.5 h / 55 °C
3: 93 percent / methanol / 3 h / Heating
4: 94 percent / PCl3 / CHCl3 / 1.) 25 deg C, 1 h, 2.) from 80 to 85 deg C, 0.5 h
5: 61 percent / 90percent HNO3, 98percent H2SO4 / 1 h / 80 - 85 °C
6: 98 percent / m-chloroperbenzoic acid / CHCl3 / 36 h / 25 °C
7: 61 percent / 3 h / 120 - 122 °C
8: 52 percent / aq. KOH / 24 h / 25 °C
9: 82 percent / KMnO4, Na2CO3 / H2O / 4 h / 25 °C
10: 96 percent / 48percent aq. HBr / 4 h / 80 - 82 °C
View Scheme
参考文献
Chu, Wenhua; Kamitori, Shigehiro; Shinomiya, Miho; Carlson, Robert G.; Takusagawa, Fusao
Journal of the American Chemical Society, 1994 , vol. 116, # 6 p. 2243 - 2253
反应条件
1: 93 percent / methanol / 3 h / Heating
2: 94 percent / PCl3 / CHCl3 / 1.) 25 deg C, 1 h, 2.) from 80 to 85 deg C, 0.5 h
3: 61 percent / 90percent HNO3, 98percent H2SO4 / 1 h / 80 - 85 °C
4: 98 percent / m-chloroperbenzoic acid / CHCl3 / 36 h / 25 °C
5: 61 percent / 3 h / 120 - 122 °C
6: 52 percent / aq. KOH / 24 h / 25 °C
7: 82 percent / KMnO4, Na2CO3 / H2O / 4 h / 25 °C
8: 96 percent / 48percent aq. HBr / 4 h / 80 - 82 °C
View Scheme
参考文献
Chu, Wenhua; Kamitori, Shigehiro; Shinomiya, Miho; Carlson, Robert G.; Takusagawa, Fusao
Journal of the American Chemical Society, 1994 , vol. 116, # 6 p. 2243 - 2253
反应条件
1: 98 percent / m-chloroperbenzoic acid / CHCl3 / 36 h / 25 °C
2: 61 percent / 3 h / 120 - 122 °C
3: 52 percent / aq. KOH / 24 h / 25 °C
4: 82 percent / KMnO4, Na2CO3 / H2O / 4 h / 25 °C
5: 96 percent / 48percent aq. HBr / 4 h / 80 - 82 °C
View Scheme
参考文献
Chu, Wenhua; Kamitori, Shigehiro; Shinomiya, Miho; Carlson, Robert G.; Takusagawa, Fusao
Journal of the American Chemical Society, 1994 , vol. 116, # 6 p. 2243 - 2253
反应条件
1: 82 percent / KMnO4, Na2CO3 / H2O / 4 h / 25 °C
2: 96 percent / 48percent aq. HBr / 4 h / 80 - 82 °C
View Scheme
参考文献
Chu, Wenhua; Kamitori, Shigehiro; Shinomiya, Miho; Carlson, Robert G.; Takusagawa, Fusao
Journal of the American Chemical Society, 1994 , vol. 116, # 6 p. 2243 - 2253
反应条件
1: 52 percent / aq. KOH / 24 h / 25 °C
2: 82 percent / KMnO4, Na2CO3 / H2O / 4 h / 25 °C
3: 96 percent / 48percent aq. HBr / 4 h / 80 - 82 °C
View Scheme
参考文献
Chu, Wenhua; Kamitori, Shigehiro; Shinomiya, Miho; Carlson, Robert G.; Takusagawa, Fusao
Journal of the American Chemical Society, 1994 , vol. 116, # 6 p. 2243 - 2253