bromine in neat (no solvent) fluorination of PBr3 with SbF3 using Br2 as catalyst;;
参考文献
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937
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Gmelin Handbook: P: MVol.C, 222, page 509 - 511
in neat (no solvent) passing gaseous PBr3 over CaF2, heated to 200°C;;
参考文献
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937
Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 222, page 509 - 511
in neat (no solvent) fluorination with CaF2 at 200°C;;
参考文献
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937
Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 216, page 496 - 498
in neat (no solvent) byproducts: PF3, (C2H5)2NPBr2; exclusion of moisture, mixt. heated to 70-75°C with stirring for2 h, N2 stream maintained during react.; fractionated (-90, -135 and -196°C), BrPF2 collected in the -135°C trap;
参考文献
Albers, W.; Krueger, W.; Storzer, W.; Schmutzler, R.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1985 , vol. 15, p. 187 - 196
in chloroform-d1 absence of air and moisture; equimolar amts., room temp.; not isolated, reaction followed by (1)H- and (31)P-NMR spectroscopy;
参考文献
Ebsworth, E. A. V.; Rankin, David W. H.; Wright, John G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1065 - 1069
in neat (no solvent) vacuum line; equimolar amts., warming to room temp.; fractionation;
参考文献
Arnold, David E. J.; Cromie, Ernest R.; Rankin, David W. H.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 1999 - 2004
in chloroform-d1 absence of air and moisture; equimolar amts., room temp.; not isolated, reaction followed by (1)H- and (31)P-NMR spectroscopy;
参考文献
Ebsworth, E. A. V.; Rankin, David W. H.; Wright, John G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1065 - 1069
in neat (no solvent) partial decomposition on standing;;
参考文献
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937
Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 222, page 509 - 511
in neat (no solvent) byproducts: AgBr; performed in the absence of light; silver hyponitrite placed in a Fisher-Porter tube wrapped in aluminum foil; F2PBr gas condensed into the tube; mixture warmed to room temp. and kept for 2 h; product passed through traps: the -130°C trap contained a mixtureof F2PBr and F2POPF2, the -160°C trap contained N2O;
参考文献
Joo, Hyun; Biswas, M. A. Salam; Hill, William E.; McKee, Michael L.
Journal of Physical Chemistry A, 2005 , vol. 109, # 7 p. 1420 - 1429
