in neat (no solvent)
passing an equimolar mixt. of PCl3 and PF3 through a glass tube containing porcelain pieces heated with an electric furnace; temp. of the formed gases 200 °C;; 50 percent of the mixt. are caused to react;;
参考文献
Booth, H. S.; Bozarth, A. R.
Journal of the American Chemical Society, 1933 , vol. 55, p. 3890 - 3890
in neat (no solvent)
addn. of 175 g powdered SbF3 to a mixt. of 130 g PCl3 and 2 g PCl5 (catalyst) in a round bottom flask with reflux condenser; keeping temp. of the vessel at 40 °C; sampling PFCl2 in a gas trap (liquid O2);;
in neat (no solvent)
contact of PCl3 vapor with heated CaF2;;
参考文献
Booth, H. S.; Bozarth, A. R.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2927 - 2934
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Gmelin Handbook: P: MVol.C, 210, page 482 - 484
in neat (no solvent)
byproducts: (C2H5)2NPCl2; ice-cooled solns. mixed, heated to 60-70°C with stirring for 5-6h, N2 stream maintained during react.; condensed from the N2-stream (-78, -105 and -196°C), Cl2PF collected in the -105°C trap;
参考文献
Albers, W.; Krueger, W.; Storzer, W.; Schmutzler, R.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1985 , vol. 15, p. 187 - 196
