反式-1,2-二氯乙烯合成路线 （共 182 条）
反应条件
1: trans-1,2-dichloroethylene With n-butyllithium in tetrahydrofuran; hexane T=0°C; 2: chloro-diphenylphosphine in tetrahydrofuran; hexane T=0°C; 3: chloro-diphenylphosphine Further stages;
参考文献
Nagaki, Aiichiro; Matsuo, Chika; Kim, Songhee; Saito, Kodai; Miyazaki, Atsuo; Yoshida, Jun-Ichi
Angewandte Chemie - International Edition, 2012 , vol. 51, # 13 p. 3245 - 3248
反应条件
T=130 - 135°C; P=36775.4 Torr;
参考文献
Schmerling; West
Journal of the American Chemical Society, 1949 , vol. 71, p. 2016
反应条件
cesium fluoride; tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis(di-tert-butylphosphino)biphenyl in 1,4-dioxane T=70°C; Suzuki coupling;
参考文献
Barluenga, Jose; Moriel, Patricia; Aznar, Fernando; Valdes, Carlos
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 3 p. 347 - 353
反应条件
T=250°C; Diels-Alder Cycloaddition; 24 h;
参考文献
Tetrahedron Letters, , vol. 54, # 15 p. 1991 - 1993
反应条件
in benzene T=50°C; 24 h; Product distributionMechanism;
参考文献
Journal of the American Chemical Society, , vol. 106, # 12 p. 3584 - 3589
反应条件
in benzene T=60°C; 24 h; effect of temperature, molar ratio; MechanismProduct distribution;
参考文献
Journal of the American Chemical Society, , vol. 106, # 12 p. 3584 - 3589
反应条件
in benzene T=70°C; 48 h; Product distributionMechanism;
参考文献
Journal of the American Chemical Society, , vol. 106, # 12 p. 3584 - 3589
反应条件
in benzene T=70°C; 24 h; var. solvents, var. additives; Product distributionMechanism;
参考文献
Lambert, Joseph B.; Boch, Richard J.; Larson, Eric G.
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3054 - 3059
反应条件
fluorine in various solvent(s) T=-75°C; 8 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Conte, L.; Gambaretto, G. P.; Napoli, M.; Gervasutti, C.
Journal of Fluorine Chemistry, 1988 , vol. 38, p. 319 - 326
反应条件
2,2,6,6-tetramethylpiperidinyl-lithium in tetrahydrofuran byproducts: C10H21CCH; -90°C, 15 min, then -15 - 20°C, 2 h;
参考文献
Kasatkin, Aleksandr; Whitby, Richard J.
Journal of the American Chemical Society, 1999 , vol. 121, # 30 p. 7039 - 7049
