反式-1,2-二氯乙烯合成路线 (共 182 条)
反应条件
2,2,6,6-tetramethylpiperidinyl-lithium in tetrahydrofuran byproducts: (E)-3-dodecen-1-yne; -90°C, 15 min, then -15 - 20°C, 2 h;
参考文献
Kasatkin, Aleksandr; Whitby, Richard J.
Journal of the American Chemical Society, 1999 , vol. 121, # 30 p. 7039 - 7049
反应条件
2 h; Irradiationstereoselectivity, different reaction conditions; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 102, # 19 p. 6108 - 6113
反应条件
cesium fluoride; tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis(di-tert-butylphosphino)biphenyl in 1,4-dioxane T=70°C; Suzuki coupling;
参考文献
Barluenga, Jose; Moriel, Patricia; Aznar, Fernando; Valdes, Carlos
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 3 p. 347 - 353
反应条件
air in neat (no solvent, gas phase) Kinetics; byproducts: HCOCl, CHCl2COCl, Cl2HCCOH; Irradiation (UV/VIS); photolysis of mixture of Cl2, ClHCCClH, air, 298 K, 1 atm; further byproducts (HCl, CO); not isolated, mass spectrometry, IR;
参考文献
Morozov; Nielsen; Morozova; Vasiliev; Loukhovitskaya
Russian Chemical Bulletin, 2010 , vol. 59, # 4 p. 754 - 760
参考文献
Journal of the American Chemical Society, , vol. 106, p. 2128
反应条件
hexafluorobenzene 4 h; Irradiation; Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 53, # 3 p. 675 - 677
反应条件
hexafluorobenzene 4 h; Irradiation; Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 53, # 3 p. 675 - 677
反应条件
24 h; Irradiation; Product distributionMechanism;
参考文献
Gaspar,P.P.; Lin,C.T.; Dunbar,B.L.
Journal of the American Chemical Society, 1984 , vol. 106, p. 2128
反应条件
4 h; Irradiationreaction without trans-1,2-dichloroethylene; var. reactions; MechanismProduct distribution;
参考文献
Journal of Organic Chemistry, , vol. 53, # 3 p. 675 - 677
参考文献
Mirskova,A.N. et al.
Journal of Organic Chemistry USSR (English Translation), 1979 , vol. 15, p. 1652 - 1659
Zhurnal Organicheskoi Khimii, 1979 , vol. 15, p. 1834 - 1839