3,4,5-三氟苯基溴化镁合成路线 （共 21 条）
反应条件
anhydrous iron chloride; N,N,N',N,-tetramethylethylenediamine; zinc(II) chloride in tetrahydrofuran T=20 - 60°C; Inert atmosphere;
参考文献
Chemical Communications, , # 10 p. 1216 - 1218
反应条件
anhydrous iron chloride; bis(1,2-diphenylphosphino)benzene; zinc(II) chloride in tetrahydrofuran T=20 - 60°C; Inert atmosphere;
参考文献
Chemical Communications, , # 10 p. 1216 - 1218
反应条件
anhydrous iron chloride; DPPEn; zinc(II) chloride in tetrahydrofuran T=20 - 60°C; Inert atmosphere;
参考文献
Chemical Communications, , # 10 p. 1216 - 1218
反应条件
FeCl2(dppbz)2; zinc(II) chloride in tetrahydrofuran T=20 - 60°C; Inert atmosphere;
参考文献
Chemical Communications, , # 10 p. 1216 - 1218
参考文献
Societe de Recherches et d'Applications Scientifiques (S.C.R.A.S.)
Patent: US6815546 B2, 2004 ;
参考文献
Societe de Recherches et d'Applications Scientifiques (S.C.R.A.S.)
Patent: US6815546 B2, 2004 ;
参考文献
Societe de Recherches et d'Applications Scientifiques (S.C.R.A.S.)
Patent: US6815546 B2, 2004 ;
参考文献
Societe de Recherches et d'Applications Scientifiques (S.C.R.A.S.)
Patent: US6815546 B2, 2004 ;
反应条件
1: (3,4,5-trifluorophenyl)magnesium bromide With zinc(II) chloride in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=30°C; 0.166667 h;
2: RR 265 With PEPPSI™-IPr catalyst in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=25 - 50°C; 6 h;
参考文献
BASF SE
Patent: US2011/301356 A1, 2011 ;
Location in patent: Page/Page column 10 ;
反应条件
1: (3,4,5-trifluorophenyl)magnesium bromide With zinc(II) chloride in tetrahydrofuran
T=25°C; 0.5 h;
2: 2-chloro-aniline With PEPPSI™-IPr catalyst in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=25°C; 6.5 h; Reflux;
参考文献
BASF SE
Patent: US2011/301356 A1, 2011 ;
Location in patent: Page/Page column 9 ;
