hydrogen; 10 palladium on activated carbon in ethanol; ethyl acetate P=1034.32 - 1965.21 Torr; 0.5 h;
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Piotrowski, David W.; Rogers, Bruce N.; McWhorter JR., William W.; Walker, Daniel Patrick; Corbett, Jeffrey W.; Groppi JR., Vincent E.; Rudmann, Daniel G.
Patent: US2003/236287 A1, 2003 ;
Location in patent: Page 35 ;
US 20030236287 A1
1: 53 percent / 0.25 h / 215 °C / microwave irradiation 2: 93 percent / K2CO3 / acetone / 2 h / 60 °C 3: 85 percent / [RuClH(CO)(PPh3)3] / CH2Cl2 / 14 h / 65 °C 4: 92 percent / ((Mes)2C3H5N2)Cl2Ru=CHPh / toluene / 3 h / 90 °C View Scheme
参考文献
Van Otterlo, Willem A.L.; Morgans, Garreth L.; Madeley, Lee G.; Kuzvidza, Samuel; Moleele, Simon S.; Thornton, Natalie; De Koning, Charles B.
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