1: 1,3-diphenyl-2-propenyl acetate With bis(η3-allyl-μ-chloropalladium(II)); (R,R)-DACH phenyl Trost's ligand in tetrahydrofuran 0.5 h; Inert atmosphere; 2: p-toluenesulfinic acid sodium salt in tetrahydrofuran T=20°C; Inert atmosphere; optical yield given as percent eeenantioselective reaction;

bis(η3-allyl-μ-chloropalladium(II)); (2R,5S)-2-(meta-carboran-9-yloxy)-3-phenyl-1,3-diaza-2-phosphabicyclo[3.3.0]octane in tetrahydrofuran T=20°C; 48 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;