反应条件
CF3COOH in tetrahydrofuran byproducts: {N(P(C6H5)3)2}{CF3COO}; all manipulations under N2 or Ar; combining the cluster with (PPN)I, addn. of CF3COOH, stirring for ca. 12 h; removal of the solvent (vac.), chromy. (silica gel, 1:9 CH2Cl2/hexane, first band Os3(CO)12, second band Os3(exo-μ2-N(H)Ph)(μ2-I)(CO)10, third band product (recrystn. from pentane; elem. anal.), forth band Os3(endo-μ2-N(H)Ph)(μ2-I)(CO)10;
参考文献
Organometallics, , vol. 11, p. 1242 - 1255
