in N,N-dimethyl-formamide
Electrolysis; -1.80 to -1.85 V vs. SCE; 0°C; 73.+-.5 mA; 2 C equivs. per mole of (C13H10)Cr(CO)3, anode: Pt-grid, cathode: Hg-pool, supporting electrolyte: 0.1M Bu4NPF6; column chromy. (1/9 diethyl ether/hexane); filtration; elem.anal.;
参考文献
Gautheron, B.; Degrand, C.; Bikrani, M.
Journal of Organometallic Chemistry, 1986 , vol. 312, p. 207 - 220
in N,N-dimethyl-formamide
Electrolysis; 22°C, -1.91 to -1.95 V vs. SCE, 2 C equivs. per mole of (C6H5)CH2(C13H9)Cr(CO)3, anode: Pt-grid, cathode: Hg-pool, supporting electrolyte: 0.1M Bu4NPF6; column chromy. (3/7 diethyl ether/hexane); elem.anal.;
参考文献
Gautheron, B.; Degrand, C.; Bikrani, M.
Journal of Organometallic Chemistry, 1986 , vol. 312, p. 207 - 220
in tetrahydrofuran
Electrolysis; -1.60 to -1.88 V vs. SCE; 0°C; 73.+-.5 mA; 2 C equivs. per mole of (C13H10)Cr(CO)3, anode: Pt-grid, cathode: Hg-pool, supporting electrolyte: 0.1M Bu4NPF6; elem.anal.;
参考文献
Gautheron, B.; Degrand, C.; Bikrani, M.
Journal of Organometallic Chemistry, 1986 , vol. 312, p. 207 - 220
in N,N-dimethyl-formamide
Electrolysis; 22°C, -1.91 to -1.95 V vs. SCE, 1.0 C equiv. per mole of (C6H5)CH2(C13H9)Cr(CO)3, anode: Pt-grid, cathode: Hg-pool, supporting electrolyte: 0.1M Bu4NPF6; column chromy. (3/7 diethyl ether/hexane); elem.anal.;
参考文献
Gautheron, B.; Degrand, C.; Bikrani, M.
Journal of Organometallic Chemistry, 1986 , vol. 312, p. 207 - 220