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63148-62-9
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
1575-47-9
合成路线
(共 59 条)
38111-44-3
苯基溴化锌
+
471931-08-5
→
反应条件
1575-47-9
反应条件
Cl2Ni(1,2-bis(diphenylphosphino)ethane) in tetrahydrofuran T=50 - 60°C;
参考文献
Wu, Jie; Sun, Xiaoyu; Zhang, Liang
Chemistry Letters, 2005 , vol. 34, # 6 p. 796 - 797
→
反应条件
1575-47-9
反应条件
palladium diacetate in methanol T=20°C; Heck reaction; 24 h; Inert atmosphereDarkness; regioselective reaction;
参考文献
Cacchi, Sandro; Fabrizi, Giancarlo; Goggiamani, Antonella; Sferrazza, Alessio
Synlett, 2009 , # 8 p. 1277 - 1280
→
反应条件
1575-47-9
反应条件
1: 3,4,5-trimethoxyphenylboronic acid With potassium carbonate in tetrahydrofuran; water Suzuki Coupling; 0.0833333 h; Inert atmosphere; 2: 5-oxo-2,5-dihydrofuran-3-yl 4-nitrobenzenesulfonate With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct in tetrahydrofuran; water T=30°C; Suzuki-Miyaura Coupling; 1 h; Inert atmosphere;
参考文献
Cheval, Nicolas P.; Dikova, Anna; Blanc, Aurelien; Weibel, Jean-Marc; Pale, Patrick
Chemistry - A European Journal, 2013 , vol. 19, # 27 p. 8765 - 8768
189078-68-0
+
98-80-6
苯硼酸
→
反应条件
1575-47-9
反应条件
PPh3 gold(I) chloro complex; 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate) in water; acetonitrile T=40°C; 2.16667 h; Schlenk techniqueInert atmosphere;
参考文献
Zhang, Rui; Xu, Qin; Chen, Kai; Gu, Peng; Shi, Min
European Journal of Organic Chemistry, 2013 , # 32 p. 7366 - 7371
84735-60-4
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反应条件
1575-47-9
反应条件
sulfuric acid in methanol 1.5 h; Heating;
参考文献
Okazaki, Renji; Negishi, Yoshio; Inamoto, Naoki
Journal of Organic Chemistry, 1984 , vol. 49, # 20 p. 3819 - 3824
222712-39-2
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反应条件
1575-47-9
反应条件
triethylamine; lithium bromide in tetrahydrofuran 4 h; Ambient temperature;
参考文献
Demir, Ayhan S.; Camkerten, Nurettin; Gercek, Zuhal; Duygu, Nese; Reis, Omer; Arikan, Elif
Tetrahedron, 1999 , vol. 55, # 8 p. 2441 - 2448
1289389-84-9
+
98-80-6
苯硼酸
→
反应条件
1575-47-9
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethanol; water; toluene T=80°C; Suzuki coupling; 2 h;
参考文献
Lamande-Langle; Ngi, S. Inack; Anselmi; Allouchi; Duchene; Abarbri; Thibonnet
Synthesis, 2011 , # 1 p. 154 - 160
201230-82-2
+
536-74-3
苯乙炔
→
反应条件
1575-47-9
+
57200-23-4
+
104-55-2
肉桂醛
反应条件
hydrogen; [Re(CO)5]H in hexane P=32253.2 Torr; 2 h; Autocalve; Product distribution / selectivity;
参考文献
AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH; LI, Chuanzhao; JACOB, Chacko; KANICHI, Sa-Ei; GARLAND, Marc
Patent: WO2011/28180 A1, 2011 ;
Location in patent: Page/Page column 16-17 ;
1008-73-7
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反应条件
1575-47-9
反应条件
N-bromosuccinmide; 2,2'-azo-bisisobutyronitrile in tetrachloromethane Heating;
参考文献
Mehta, Goverdhan; Sengupta, Saumitra
Tetrahedron Letters, 1996 , vol. 37, # 47 p. 8625 - 8626
5123-13-7
5,5-二甲基-2-苯基-1,3,2-二氧硼杂
+
117968-51-1
→
反应条件
1575-47-9
+
1214319-65-9
反应条件
1: With anhydrous copper acetate in methanol T=28°C; 24 h; Inert atmosphere; 2: With hydrogenchloride in methanol; water T=20°C; 1 h; Inert atmosphere;
参考文献
Yamamoto, Yoshihiko; Kirai, Naohiro
Heterocycles, 2010 , vol. 80, # 1 p. 269 - 279
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