1,4-二乙酰氧基-2-丁烯合成路线 （共 39 条）
反应条件
sulfuric acid; acetic acid T=90°C; 3.5 h;
参考文献
Talipov, R. F.; Faizrakhmanov, I. S.; Rakhmankulov, E. D.; Safarova, V. G.
Journal of Organic Chemistry USSR (English Translation), 1989 , vol. 25, # 3.1 p. 438 - 440
Zhurnal Organicheskoi Khimii, 1989 , vol. 25, # 3 p. 488 - 491
参考文献
Nasarow et al.
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 1132,1134,1140;engl.Ausg.S.1195,1196,1201
反应条件
triphenylphosphine; platinum (II) chloride T=120 - 160°C; P=76.0051 - 760.051 Torr; 12 - 14.5 h; Heating / reflux; Product distribution / selectivity;
参考文献
US2009/54717 A1, ;
Page/Page column 4-5 ;
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=70 - 72°C; Product distribution;
参考文献
European Journal of Organic Chemistry, , # 17 p. 3301 - 3305
反应条件
Grubb's 2nd generation catalyst in water T=20°C; 15 h; Micellar solution; optical yield given as percent destereoselective reaction;
参考文献
Ablialimov, Osman; Kedziorek, Mariusz; Torborg, Christian; Malinska, Maura; Wozniak, Krzysztof; Grela, Karol
Organometallics, 2012 , vol. 31, # 21 p. 7316 - 7319
反应条件
hydrogenchloride; diethyl ether; water in ethanol 16 h; Inert atmosphereReflux;
参考文献
Stehouwer, Jeffrey S.; Daniel, Lauryn M.; Chen, Ping; Voll, Ronald J.; Williams, Larry; Plott, Susan J.; Votaw, John R.; Owens, Michael J.; Howell, Leonard; Goodman, Mark M.
Journal of Medicinal Chemistry, 2010 , vol. 53, # 15 p. 5549 - 5557
反应条件
sodium tetrahydroborate; water; dihydridotetrakis(triphenylphosphine)ruthenium(II) in toluene T=100°C; 22 h;
参考文献
Tetrahedron Letters, , vol. 47, # 50 p. 8943 - 8944
反应条件
1: K2CO3, MeOH / 0.17 h / 0 °C 2: PPh3, CCl4 / 20 h / Heating View Scheme
参考文献
Terakado, Masahiko; Murai, Kouya; Miyazawa, Masahiro; Yamamoto, Keiji
Tetrahedron, 1994 , vol. 50, # 19 p. 5705 - 5718
反应条件
formic acid; triethylamine; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tributylphosphine in tetrahydrofuran 2 h; Heating;
参考文献
Tsuji, Jiro; Minami, Ichiro; Shimizu, Isao
Synthesis, 1986 , # 8 p. 623 - 627
反应条件
copper(I) bromide; lithium bromide 1.) THF, -50 deg C, 15 min; 2.) -70 deg C, 12 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Carpita, Adriano; Rossi, Renzo
Synthesis, 1982 , # 6 p. 469 - 471
