ethanol in hexane byproducts: ethane; Ar, ethanol in hexane added dropwise to a soln. of AlEt3 at -30°C; hexane was distilled off; residue was vac. distilled;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 32, # 5 p. 1006 - 1011
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 5 p. 1113 - 1118
in neat (no solvent, gas phase) byproducts: ethane, ethene, butene; decompn. on heating to 479 K; mechanism discussed; volatiles detected by GC; mixt. of Al and Al2O3 as residue;
参考文献
Baev
Russian Journal of Physical Chemistry A, 2004 , vol. 78, # 9 p. 1362 - 1370
in benzene molar ratio nickel acetylacetonat : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h;
参考文献
Gmelin Handbook: Ni: Org.Verb.2, 1.4.2.1.1, page 87 - 88
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Studiengesellschaft Kohle m.b.H.
Patent: DE1191375 , 1965 ;
in benzene byproducts: Al(C5H7O2)3; 0°C; molar ratio of Ni(C5H7O2)2:1,5-cyclooctadiene:(C2H5)2AlOC2H5= 1:2.5:2.3; 2.5h; solvolyse with ethanol and 2nHCl below 5°C; distn. in high vacuum at 40-50°C; cooling and crystn.;
