1: (4-methoxyphenyl)methanol With n-butyllithium in tetrahydrofuran
2: With methyl iodide in tetrahydrofuran
T=20°C; 1 h;
3: benzyl-magnesium bromide in tetrahydrofuran
T=20°C; 1 h;
in diethyl ether
addn. of Et3GeBr soln. to a soln. of benzylmagnesium bromide, refluxingovernight; hydrolyzing (ice, aq. HCl), column chromy. (silica gel, hexane), fractional distn;
参考文献
Kobayashi, Masanori; Yoshida, Masato; Kobayashi, Michio
Bulletin of the Chemical Society of Japan, 1986 , vol. 59, p. 3169 - 3174
