toluene-4-sulfonic acid in ethylene glycol; ethyl acetate; toluene

hydrogenchloride; AlCl3 in hexane; nitrobenzene

sodium hydroxide; sodium hypochlorite in 1,4-dioxane; water

sodium hydroxide; sodium hypochlorite in (2S)-N-methyl-1-phenylpropan-2-amine hydrate; water

pyridine; water; iodine in methanol T=30°C; other temperatures; ΔH(excit.); KineticsMechanismThermodynamic data;

pyridine; water; iodine in methanol T=30°C; other temperatures; ΔH(excit.); KineticsMechanismThermodynamic data;

1: copper(l) iodide; potassium carbonate; N-methyl-2-(methylamino)ethylamine / toluene / 24 h / 110 °C / Inert atmosphere 2: trifluoroacetic acid / dichloromethane / 3 h / 0 - 20 °C View Scheme

<b>Multi-step reaction with 2 steps<br /> </b>1.1: potassium carbonate / dichloromethane; water / 1 h<br />2.1: tetrahydrofuran; 2-methyl tetrahydrofuran / 1.5 h / 10 - 15 &deg;C / Inert atmosphere<br />2.2: Cooling with ice<br /> <br /> &nbsp;

Stage #1: <b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '11323438', constants.ctx, '0')">aluminum (III) chloride</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '507540', constants.ctx, '0')">nitrobenzene</a> <br />T=100&deg;C;&nbsp;4&nbsp;h;&nbsp;<br />Stage #2: <b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '3587155', constants.ctx, '0')">water</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '507540', constants.ctx, '0')">nitrobenzene</a> <br /> <br /> <br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '605283', constants.ctx, '0')">triethylamine</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '11324644', constants.ctx, '0')">palladium diacetate</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '2821785', constants.ctx, '0')">1,3-bis-(diphenylphosphino)propane</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '605365', constants.ctx, '0')">N,N-dimethyl-formamide</a> <br />T=60&deg;C;&nbsp;<br /> &nbsp;