2-苯基-1-乙炔硼酸频那醇酯合成路线 （共 36 条）
反应条件
1.1: Schwartz's reagent / dichloromethane / 1 h / 20 °C / Inert atmosphere 1.2: Inert atmosphere 2.1: (η-1,5-cyclooctadiene) {[4(R),5(R)]-1-benzoyl-2-[(S)-2-diphenylphosphinoferrocenyl]-4,5-diphenyl-4,5-dihydro-1-imidazole} iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen / dichloromethane / 12 h / 50 °C / 7500.75 Torr View Scheme
参考文献
Gaziaesmiloviae, Ivana; Casas-Arce, Eva; Roseblade, Stephen J.; Nettekoven, Ulrike; Zanotti-Gerosa, Antonio; Kovacevic, Miroslav; Casar, Zdenko
Angewandte Chemie - International Edition, 2012 , vol. 51, # 4 p. 1014 - 1018
反应条件
1.1: Schwartz's reagent / dichloromethane / 1 h / 20 °C / Inert atmosphere 1.2: Inert atmosphere 2.1: (tricyclohexylphosphine)(1,5-cyclooctadiene)pyridineiridium(I) hexafluorophosphate; hydrogen / dichloromethane / 12 h / 50 °C / 7500.75 Torr View Scheme
参考文献
Gaziaesmiloviae, Ivana; Casas-Arce, Eva; Roseblade, Stephen J.; Nettekoven, Ulrike; Zanotti-Gerosa, Antonio; Kovacevic, Miroslav; Casar, Zdenko
Angewandte Chemie - International Edition, 2012 , vol. 51, # 4 p. 1014 - 1018
反应条件
1.1: Schwartz's reagent / tetrahydrofuran / 1 h / 20 °C / |Inert atmosphere 1.2: 1 h / 20 °C / |Inert atmosphere 2.1: hydrogen; Ir-(4S,5S)-ThrePHOX / dichloromethane / 18 h / 50 °C / 22502.3 Torr View Scheme
参考文献
Roseblade, Stephen J.; Smilovic, Ivana Gazic; Casar, Zdenko
Tetrahedron, 2014 , vol. 70, # 16 p. 2654 - 2660
反应条件
1.1: Schwartz's reagent / dichloromethane / 1 h / 20 °C / Inert atmosphere 1.2: Inert atmosphere 2.1: (η-1,5-cyclooctadiene) {[4(R),5(R)]-1-benzoyl-2-[(S)-2-diphenylphosphinoferrocenyl]-4,5-diphenyl-4,5-dihydro-1-imidazole} iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen / dichloromethane / 12 h / 50 °C / 3750.38 Torr View Scheme
参考文献
Gaziaesmiloviae, Ivana; Casas-Arce, Eva; Roseblade, Stephen J.; Nettekoven, Ulrike; Zanotti-Gerosa, Antonio; Kovacevic, Miroslav; Casar, Zdenko
Angewandte Chemie - International Edition, 2012 , vol. 51, # 4 p. 1014 - 1018
反应条件
1.1: Schwartz's reagent / tetrahydrofuran / 1 h / 20 °C / |Inert atmosphere 1.2: 1 h / 20 °C / |Inert atmosphere 2.1: hydrogen; (C5H2N(C6H5))CH2CH2CH(O)P(C(CH3)3)2Ir(C8H12)(1+)*B(C8H3F6)4(1-)=(C5H2N(C6H5))CH2CH2CH(O)P(C(CH3)3)2Ir(C8H12)B(C8H3F6)4 / dichloromethane / 18 h / 50 °C / 22502.3 Torr View Scheme
参考文献
Roseblade, Stephen J.; Smilovic, Ivana Gazic; Casar, Zdenko
Tetrahedron, 2014 , vol. 70, # 16 p. 2654 - 2660
反应条件
1.1: zirconocene dichloride; n-butyllithium; tributylphosphine / tetrahydrofuran; hexane / 1 h / 50 °C / |Schlenk technique; |Inert atmosphere 1.2: 1 h / 50 °C / |Schlenk technique; |Inert atmosphere 2.1: RuCl2(tricyclohexylphosphine)2(benzylidene) / dichloromethane / 1 h / 20 °C / |Schlenk technique; |Inert atmosphere 3.1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium hydroxide / tetrahydrofuran; water / 24 h / 20 °C / |Schlenk technique; |Inert atmosphere View Scheme
参考文献
Nishihara, Yasushi; Suetsugu, Masato; Saito, Daisuke; Kinoshita, Megumi; Iwasaki, Masayuki
Organic Letters, 2013 , vol. 15, # 10 p. 2418 - 2421
反应条件
copper(l) chloride in DMI T=120°C; 0.5 h; Inert atmosphere;
参考文献
Nishihara, Yasushi; Saito, Daisuke; Inoue, Eiji; Okada, Yoshiaki; Miyazaki, Mikihiro; Inoue, Yoshiaki; Takagi, Kentaro
Tetrahedron Letters, 2010 , vol. 51, # 2 p. 306 - 308
反应条件
[Pt(PPh3)4] in toluene (N2); addn. of phenylethynylpinacolatoborane in react. mixt. of Pt(PPh3)4 and bis(pinacolato)diborane(4) in dry toluene; stirring overnight at 80°C;
参考文献
Abu Ali, Hijazi; Al Quntar, Abed El Aziz; Goldberg, Israel; Srebnik, Morris
Organometallics, 2002 , vol. 21, # 21 p. 4533 - 4539
反应条件
1,3-dimethyl-imidazolidin-2-one; potassium carbonate; triphenylphosphine; copper(l) chloride T=120°C; 12 h;
参考文献
Ogawa, Daisuke; Li, Jing; Suetsugu, Masato; Jiao, Jiao; Iwasaki, Masayuki; Nishihara, Yasushi
Tetrahedron Letters, 2013 , vol. 54, # 6 p. 518 - 521
反应条件
1,3-dimethyl-imidazolidin-2-one; potassium carbonate; triphenylphosphine; copper(l) chloride T=120°C; 12 h;
参考文献
Tetrahedron Letters, , vol. 54, # 6 p. 518 - 521
