反应条件
Stage #1: <a href="#" onclick="return RXDsubstances(event, this, '1907245', constants.ctx, '0')">2-Bromo-1,3,5-trimethyl-benzene</a> <b>With</b> <a href="#" onclick="return RXDsubstances(event, this, '1209227', constants.ctx, '0')">n-butyllithium</a> <b>in</b> <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a>; <a href="#" onclick="return RXDsubstances(event, this, '1730733', constants.ctx, '0')">hexane</a> <br />T=-78°C; 1 h; Inert atmosphere; <br />Stage #2: <a href="#" onclick="return RXDsubstances(event, this, '16802146', constants.ctx, '0')">[AuCl(AsPh<sub>3</sub>)]</a> <b>With</b> <a href="#" onclick="return RXDsubstances(event, this, '1842037', constants.ctx, '0')">triphenyl-arsane</a> <b>in</b> <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a>; <a href="#" onclick="return RXDsubstances(event, this, '1730733', constants.ctx, '0')">hexane</a> <br />T=0°C; 0.25 h; Inert atmosphere; <br />
参考文献
Delpozo, Juan; Carrasco, Desiree; Perez-Temprano, Monica H.; Garcia-Melchor, Max; Alvarez, Rosana; Casares, Juan A.; Espinet, Pablo Angewandte Chemie - International Edition, 2013 , vol. 52, # 8 p. 2189 - 2193 Angew. Chem., 2013 , vol. 125, # 8 p. 2245 - 2249
