氰甲基苯乙烯(间位与对位混合物)合成路线 （共 4 条）
反应条件
18-crown-6 ether in acetonitrile T=20°C; 16 h;
参考文献
Zhao, Lin-Jing; Kwong, Cathy Kar-Wing; Shi, Min; Toy, Patrick H.
Tetrahedron, 2005 , vol. 61, # 51 p. 12026 - 12032
反应条件
caesium carbonate; triphenylphosphine; palladium dichloride in tetrahydrofuran; water T=80°C; 22 h; Inert atmosphereSchlenk technique;
参考文献
Yasu, Yusuke; Koike, Takashi; Akita, Munetaka
Organic Letters, 2013 , vol. 15, # 9 p. 2136 - 2139
反应条件
dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; bis(η3-allyl-μ-chloropalladium(II)) in 1,3,5-trimethyl-benzene T=20 - 140°C; 5.16667 h; Inert atmosphereSealed tube; chemoselective reaction;
参考文献
Shang, Rui; Ji, Dong-Sheng; Chu, Ling; Fu, Yao; Liu, Lei
Angewandte Chemie - International Edition, 2011 , vol. 50, # 19 p. 4470 - 4474
反应条件
1: (i) NBS, (PhCO)2O2, (ii) (heating), benzene-1,4-diol View Scheme
参考文献
Tahan,M. et al.
Israel Journal of Chemistry, 1972 , vol. 10, p. 835 - 839
