6-溴-3,4-亚甲基二氧苯甲醛合成路线 （共 110 条）
反应条件
sodium chlorite; phosphoric acid; dihydrogen peroxide in water; acetone
Ambient temperature;
参考文献
Padwa, Albert; Dimitroff, Martin; Waterson, Alex G.; Wu, Tianhua
Journal of Organic Chemistry, 1998 , vol. 63, # 12 p. 3986 - 3997
反应条件
sodium methylate in dimethyl sulfoxide
T=150°C; 0.0194444 h;
参考文献
Kobayashi, Shigeru; Imakura, Yasuhiro; Horikawa, Ritsuko
Chemical & Pharmaceutical Bulletin, 1980 , vol. 28, # 4 p. 1287 - 1293
参考文献
Fales et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 5885,5889
反应条件
in dimethyl sulfoxide
T=150°C; 0.0194444 h;
参考文献
Kobayashi, Shigeru; Imakura, Yasuhiro; Horikawa, Ritsuko
Chemical & Pharmaceutical Bulletin, 1980 , vol. 28, # 4 p. 1287 - 1293
反应条件
N-bromosuccinmide; chloroform
Behandeln der Reaktionsloesung mit Ammoniak;
参考文献
Yamaguchi
Nippon Kagaku Kaishi, 1956 , vol. 77, p. 591,592
Chem.Abstr., 1958 , p. 305
反应条件
sodium hydride
1) DMF, 2) 25 deg C, 12 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Cassels, Bruce K.; Radetski, Claudemir; Rezende, Marcos Caroli
Recueil des Travaux Chimiques des Pays-Bas, 1992 , vol. 111, # 10 p. 448 - 450
反应条件
sodium hydride
1) DMF, 2) 25 deg C, 12 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Cassels, Bruce K.; Radetski, Claudemir; Rezende, Marcos Caroli
Recueil des Travaux Chimiques des Pays-Bas, 1992 , vol. 111, # 10 p. 448 - 450
反应条件
1: 92 percent / 6 N HCl / methanol / 3.5 h / Heating
2: 1.) NaH / 1.) DMF, RT, 1 h, 2.) DMF, overnight
3: 6 N aq. HCl / benzene / Heating
View Scheme
参考文献
Aidhen, Indrapal Singh; Narasimhan, N. S.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1993 , vol. 32, # 2 p. 211 - 221
反应条件
manganese(IV) oxide; sodium cyanide; acetic acid
T=20°C; 20 h;
参考文献
Mentzel, Uffe V.; Tanner, David; Tonder, Janne E.
Journal of Organic Chemistry, 2006 , vol. 71, # 15 p. 5807 - 5810
反应条件
1: 66 percent / KMnO4 / 2-methyl-propan-2-ol; H2O / 83 °C
2: 95 percent / H2SO4 / methanol / 72 h / Heating
View Scheme
参考文献
Keck, Gary E; McLaws, Mark D; Wager, Travis T
Tetrahedron, 2000 , vol. 56, # 51 p. 9875 - 9883
