2-去苯甲酰基-7,10-二[O-(三乙基硅烷基)]-10-去乙酰基-13-O-三甲基硅烷基浆果赤霉素III合成路线 （共 4 条）
反应条件
1: With sodium bis(2-methoxyethoxy)aluminium dihydride in tetrahydrofuran; toluene T=0°C; 1 h; 2: With sodium hydrogencarbonate in tetrahydrofuran; water; toluene
参考文献
Florida State University
Patent: US6727369 B1, 2004 ;
Location in patent: Page column 40 - 41 ;
反应条件
1: With sodium bis(2-methoxyethoxy)aluminium dihydride in tetrahydrofuran; toluene T=0°C; 1 h; 2: With sodium hydrogencarbonate
参考文献
US6727369 B1, ;
Page column 43 - 44 ;
反应条件
1: 13-O-trimethylsilyl-7,10-bis-O-triethylsilyl-2-debenzoyl-4,10-bisdeacetyl baccatin (III) With lithium diisopropyl amide in tetrahydrofuran T=-78°C; 0.5 h; 2: acetyl chloride in tetrahydrofuran T=-78°C; 1 h; 3: With sodium hydrogencarbonate in tetrahydrofuran; water
参考文献
US6727369 B1, ;
Page column 50 ;
反应条件
1: 13-O-trimethylsilyl-7,10-bis-O-triethylsilyl-2-debenzoyl-4,10-bisdeacetyl baccatin (III) With lithium diisopropyl amide 2: acetyl chloride
参考文献
US6339164 B1, ;
Page column 19-20 ;
