二氯双(三甲基硅基)甲烷合成路线 （共 34 条）
反应条件
tetraethylammonium tetrafluoroborate in N,N-dimethyl-formamide electrolysis;
参考文献
Synthesis, , # 5 p. 369 - 381
反应条件
magnesium chloride in N,N-dimethyl-formamide 17.6667 h; electroreduction, anode: Mg, cathode: CV;
参考文献
Journal of Organometallic Chemistry, , vol. 358, p. 31 - 38
反应条件
tetraethylammonium tetrafluoroborate in N,N-dimethyl-formamide 17.0833 h; electroreduction, anode: Mg, cathode: stainless steel; Further byproducts given;
参考文献
Journal of Organometallic Chemistry, , vol. 358, p. 31 - 38
反应条件
tetraethylammonium tetrafluoroborate in N,N-dimethyl-formamide 29.25 h; electroreduction, anode: Zn, cathode: stainless steel;
参考文献
Journal of Organometallic Chemistry, , vol. 358, p. 31 - 38
反应条件
n-butyllithium 2.) -110 deg C; Yield given. Multistep reaction;
参考文献
Journal of Organometallic Chemistry, , vol. 437, # 1/2 p. 41 - 55
反应条件
in various solvent(s) 725 h; electroreduction, anode: Al, cathode: stainless steel; Further byproducts given;
参考文献
Journal of Organometallic Chemistry, , vol. 358, p. 31 - 38
参考文献
Journal of Organometallic Chemistry, , vol. 71, p. 377 - 392
反应条件
(i) nBuLi, iPr2NH, THF, hexane, (ii) /BRN= 1209232/; Multistep reaction;
参考文献
Journal of Organometallic Chemistry, , vol. 168, p. 13 - 21
反应条件
chloro-trimethyl-silane; LiDBB 1.) THF, -90 deg C; 2.) THF, -80 deg C; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Eikema Hommes, N. J. R. van; Bickelhaupt, F.; Klumpp, G. W.
Tetrahedron Letters, 1988 , vol. 29, # 41 p. 5237 - 5240
反应条件
LiDBB 1.) THF, -90 deg C; 2.) THF, -80 deg C; other electrophiles and temperature; Product distribution;
参考文献
Eikema Hommes, N. J. R. van; Bickelhaupt, F.; Klumpp, G. W.
Tetrahedron Letters, 1988 , vol. 29, # 41 p. 5237 - 5240
