二氯双(三甲基硅基)甲烷合成路线 （共 34 条）
反应条件
n-butyllithium 1.) hexane, THF, Et2O, n-pentane, -110 deg C, 2 h, 2.) hexane, THF, Et2O, n-pentane, a) -110 deg C, 30 min, b) -110 deg C - RT, overnight; Multistep reaction. Title compound not separated from byproducts;
参考文献
Eaborn, Colin; Jones, Karen L.; Lickiss, Paul D.
Journal of Organometallic Chemistry, 1994 , vol. 466, # 1-2 p. 35 - 42
反应条件
1.) hexane, THF, Et2O, n-pentane, -110 deg C, 2 h, 2.) hexane, THF, Et2O, n-pentane, a) -110 deg C, 30 min, b) -110 deg C - RT, overnight; Multistep reaction. Title compound not separated from byproducts;
参考文献
Eaborn, Colin; Jones, Karen L.; Lickiss, Paul D.
Journal of Organometallic Chemistry, 1994 , vol. 466, # 1-2 p. 35 - 42
反应条件
in tetrahydrofuran Ar-atmosphere; dropwise addn. of Si-compd. to 2 equiv. of Sn-compd. at 0°C, stirring for 3 h; solvent removal, recrystn. (petroleum ether); elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 564, # 1-2 p. 215 - 226
反应条件
lithium in tetrahydrofuran T=-80°C;
参考文献
Eikema Hommes, N. J. R. van; Bickelhaupt, F.; Klumpp, G. W.
Tetrahedron Letters, 1988 , vol. 29, # 41 p. 5237 - 5240
反应条件
(i) nBuLi, (ii) EtOH; Multistep reaction;
参考文献
Eisch, John J.; Galle, James E.; Piotrowski, Andrzej; Tsai, Miin-Rong
Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5051 - 5056
反应条件
n-butyllithium in tetrahydrofuran; diethyl ether; hexane; pentane T=-110 - -80°C; 2 h;
参考文献
Eaborn, Colin; Reed, David E.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 1687 - 1694
反应条件
n-butyllithium 2.) -110 deg C; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of Organometallic Chemistry, , vol. 437, # 1/2 p. 41 - 55
反应条件
1: 36 percent / 1M nBuLi / hexane; tetrahydrofuran; diethyl ether; pentane / 2 h / -110 - -80 °C 2: 97 percent / Br2 / CCl4; CH2Cl2 / 0.25 h 3: 84 percent / CH2Cl2 / 24 h View Scheme
参考文献
Aigbirhio, Franklin I.; Al-Juaid, Salih S.; Eaborn, Colin; Habtemariam, Abraha; Hitchcock, Peter B.; Smith, J. David
Journal of Organometallic Chemistry, 1991 , vol. 405, # 2 p. 149 - 160
反应条件
1: 66 percent / 1.) BuLi / hexane; tetrahydrofuran; diethyl ether; pentane / 1.) -100 deg C, 2 h; 2.) -80 deg C 2: ICl / CCl4 / 18 h / 35 °C View Scheme
参考文献
Ayoko, G. Adefikayo; Eaborn, Colin
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 381 - 384
反应条件
chloro-trimethyl-silane; LiDBB 1.) THF, -90 deg C; 2.) THF, -80 deg C; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tetrahedron Letters, , vol. 29, # 41 p. 5237 - 5240
