反式-1-苯基-1-戊烯合成路线 (共 108 条)
反应条件
(i) B2H6, (ii) (heating), (iii) aq. H2O2, aq. NaOH; Multistep reaction;
参考文献
Hubert,A.J.
Journal of the Chemical Society [Section] C: Organic, 1967 , p. 235 - 238
反应条件
copper(l) iodide; tris(triphenylphosphine)ruthenium(II) chloride; zinc in 1,4-dioxane; water
T=100°C; 36 h; Schlenk techniqueInert atmosphere; Time; chemoselective reaction;
参考文献
Schabel, Tobias; Belger, Christian; Plietker, Bernd
Organic Letters, 2013 , vol. 15, # 11 p. 2858 - 2861
反应条件
aluminum oxide; potassium fluoride; palladium
T=100°C; Suzuki reaction; 4 h;
参考文献
Kabalka, George W.; Pagni, Richard M.; Hair, C. Maxwell
Organic Letters, 1999 , vol. 1, # 9 p. 1423 - 1425
反应条件
n-butyllithium; boron trichloride in hexane; dichloromethane
T=20°C; 10 h; Title compound not separated from byproducts;
参考文献
Kabalka, George W.; Yao, Min-Liang; Borella, Scott
Journal of the American Chemical Society, 2006 , vol. 128, # 35 p. 11320 - 11321
反应条件
copper(I) bromide dimethylsulfide complex; (R,S)-Taniaphos in diethyl ether; dichloromethane
T=-75°C; 4 h;
参考文献
Lopez, Fernando; Van Zijl, Anthoni W.; Minnaard, Adriaan J.; Feringa, Ben L.
Chemical Communications, 2006 , # 4 p. 409 - 411
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; methyl-ethyl phosphite; tri-iso-propylsilane in 2-cyclohexylethanol
T=160°C; 15 h; Inert atmosphere;
参考文献
Tobisu, Mamoru; Nakamura, Ryo; Kita, Yusuke; Chatani, Naoto
Journal of the American Chemical Society, 2009 , vol. 131, p. 3174 - 3175
反应条件
tris(triphenylphosphine)ruthenium(II) chloride; hydrogen in ethanol
T=20°C; P=750.075 Torr; 12 h; optical yield given as percent de;
参考文献
Belger, Christian; Neisius, N. Matthias; Plietker, Bernd
Chemistry - A European Journal, 2010 , vol. 16, # 40 p. 12214 - 12220
反应条件
copper(I) bromide dimethylsulfide complex in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; Yields of byproduct given;
参考文献
Sekiya, Kouichi; Nakamura, Eiichi
Tetrahedron Letters, 1988 , vol. 29, # 40 p. 5155 - 5156
反应条件
dichloro bis(acetonitrile) palladium(II) in chloroform-d1
T=35°C; 24 h;
参考文献
Giles, Robin G. F.; Son, Vanessa R. Lee; Sargent, Melvyn V.
Australian Journal of Chemistry, 1990 , vol. 43, # 4 p. 777 - 781
反应条件
chloro-trimethyl-silane; benzoic acid; sodium iodide in acetonitrile
T=75°C; 20 h; Yields of byproduct given;
参考文献
Ghera, Eugene; Maurya, Rakesh; Hassner, Alfred
Tetrahedron Letters, 1989 , vol. 30, # 35 p. 4741 - 4744