反式-1-苯基-1-戊烯合成路线 (共 108 条)
反应条件
ytterbium(III) triflate
T=60°C; 8 h;
参考文献
Curini, Massimo; Epifano, Francesco; Maltese, Federica; Marcotullio, Maria Carla
European Journal of Organic Chemistry, 2003 , # 9 p. 1631 - 1634
反应条件
lithium tetrachloromanganate(II) in tetrahydrofuran
T=0°C;
参考文献
Namboothiri; Hassner, Alfred
Journal of Organometallic Chemistry, 1996 , vol. 518, # 1-2 p. 69 - 77
反应条件
1: pentanal With polystyrene-supported 4-(phenylseleno)morpholine in dichloromethane
5 h; Heating;
2: PhMgX T=0 - 20°C; 6 h;
3: With thionyl chloride; triethylamine in dichloromethane
T=20°C; 4 h;
参考文献
Sheng, Shou-Ri; Huang, Xian
Journal of the Chinese Chemical Society, 2003 , vol. 50, # 4 p. 893 - 896
反应条件
sodium hydride in N,N-dimethyl-formamide
参考文献
Buss, Antony D.; Mason, Ralph; Warren, Stuart
Tetrahedron Letters, 1983 , vol. 24, # 47 p. 5293 - 5296
反应条件
potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)); Tedicyp in N,N-dimethyl-formamide
T=130°C; Heck; 20 h;
参考文献
Berthiol, Florian; Doucet, Henri; Santelli, Maurice
Tetrahedron Letters, 2003 , vol. 44, # 6 p. 1221 - 1225
反应条件
1: butyl-triphenylphosphonium chloride With n-butyllithium in hexane; toluene
T=25°C; 0.5 h;
2: benzyl alcohol With 1,3-bis-(diphenylphosphino)propane; caesium carbonate; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium in hexane; toluene
T=150°C; 72 h; Title compound not separated from byproducts;
参考文献
Black, Phillip J.; Edwards, Michael G.; Williams, Jonathan M. J.
European Journal of Organic Chemistry, 2006 , # 19 p. 4367 - 4378
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; methyl-ethyl phosphite; tri-iso-propylsilane in ethylcyclohexane
T=160°C; 15 h; Inert atmosphere;
参考文献
Tobisu, Mamoru; Nakamura, Ryo; Kita, Yusuke; Chatani, Naoto
Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 3 p. 582 - 587
反应条件
sodium hexamethyldisilazane in tetrahydrofuran
-78 deg C -> 23 deg C;
参考文献
Maryanoff,B.E.; Reitz,A.B.; Mutter,M.S.
Journal of the American Chemical Society, 1986 , vol. 108, p. 7664
反应条件
potassium carbonate in methanol
T=65°C; 1 h; comparative studies with other arylaldehydes; Product distributionQuantum yield;
参考文献
Le Bigot, Y.; El Gharbi, R.; Delmas, M.; Gaset, A.
Tetrahedron, 1986 , vol. 42, # 14 p. 3813 - 3824
反应条件
sodium hydride in N,N-dimethyl-formamide
参考文献
Buss, Antony D.; Warren, Stuart
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 2307 - 2326