2-氨基-4-甲氧基-6-硝基甲苯合成路线 （共 11 条）
反应条件
sodium sulfide; sodium hydrogencarbonate in water 1 h; Heating;
参考文献
Buechi, George; Lee, Gary C. M.; Yang, David; Tannenbaum, Steven R.
Journal of the American Chemical Society, 1986 , vol. 108, # 14 p. 4115 - 4119
反应条件
1: 45 percent / fuming nitric acid, fuming sulfuric acid / 6 h / 80 - 90 °C 2: 57 percent / sodium / 2 h / Heating 3: 35 percent / sodium bicarbonate, sodium sulfide nonahydrate / H2O / 1 h / Heating View Scheme
参考文献
Buechi, George; Lee, Gary C. M.; Yang, David; Tannenbaum, Steven R.
Journal of the American Chemical Society, 1986 , vol. 108, # 14 p. 4115 - 4119
反应条件
1: 57 percent / sodium / 2 h / Heating 2: 35 percent / sodium bicarbonate, sodium sulfide nonahydrate / H2O / 1 h / Heating View Scheme
参考文献
Buechi, George; Lee, Gary C. M.; Yang, David; Tannenbaum, Steven R.
Journal of the American Chemical Society, 1986 , vol. 108, # 14 p. 4115 - 4119
反应条件
1: aqueous KOH 2: sodium disulfide; aqueous acetone View Scheme
参考文献
Pailer,M.; Bergthaller,P.
Monatshefte fuer Chemie, 1967 , vol. 98, # 3 p. 579 - 591
反应条件
1: aqueous H2SO4 / <0 / Diazotization.Eintragen der Diazoniumsalz-Loesung in siedende wss. CuSO4-Loesung 2: aqueous KOH 3: sodium disulfide; aqueous acetone View Scheme
参考文献
Curd; Robertson
Journal of the Chemical Society, 1933 , p. 437,440
参考文献
Curd; Robertson
Journal of the Chemical Society, 1933 , p. 437,440
参考文献
Curd; Robertson
Journal of the Chemical Society, 1933 , p. 437,440
反应条件
1: 58 percent / 1.) sodium nitrite, 12M HCl; 2.) copper(I) chloride / H2O / 0 - 5 °C / 2.) 10 min 2: 1.) pyrrolydine; 2.) H2 / 2.) 5percent palladium on charcoal / 1.) DMF, reflux, 3 h; 2.) 4 atm View Scheme
参考文献
Buechi, George; Lee, Gary C. M.; Yang, David; Tannenbaum, Steven R.
Journal of the American Chemical Society, 1986 , vol. 108, # 14 p. 4115 - 4119
反应条件
1: (i) aq. NaNO2, H2SO4, (ii) CuSO4 2: K2CO3 / dimethylformamide View Scheme
参考文献
Pailer,M.; Bergthaller,P.
Monatshefte fuer Chemie, 1967 , vol. 98, # 3 p. 579 - 591
反应条件
hydrogenchloride; copper(l) chloride; sodium nitrite in water T=0 - 5°C; 2.) 10 min;
参考文献
Buechi, George; Lee, Gary C. M.; Yang, David; Tannenbaum, Steven R.
Journal of the American Chemical Society, 1986 , vol. 108, # 14 p. 4115 - 4119
