(E)-2,2,7,7-四甲基-2,7-二硅杂辛-4-烯合成路线 （共 19 条）
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide 24 h; Ambient temperature;
参考文献
Hiyama, Tamejiro; Obayashi, Michio; Mori, Ichiro; Nozaki, Hitosi
Journal of Organic Chemistry, 1983 , vol. 48, # 6 p. 912 - 914
反应条件
magnesium in tetrahydrofuran
参考文献
Bock,H.; Seidl,H.
Journal of Organometallic Chemistry, 1968 , vol. 13, p. 87 - 102
反应条件
lithium in tetrahydrofuran Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Biran, C.; Dunogues, J.; Calas, R.; Gerval, J.; Tskhovrebachvili, T.
Synthesis, 1981 , # 3 p. 220 - 222
反应条件
1: buta-1,3-diene With lithium in tetrahydrofuran T=0 - 20°C; Inert atmosphere; 2: chloro-trimethyl-silane in tetrahydrofuran T=0 - 20°C; Inert atmosphere;
参考文献
Aouf, Chahinez; El Abed, Douniazad; Giorgi, Michel; Santelli, Maurice
Tetrahedron, 2009 , vol. 65, # 28 p. 5563 - 5570
反应条件
bis(1,5-cyclooctadiene)nickel (0); diethylaluminium chloride; triphenylphosphine in toluene T=50°C; 48 h; other ligands, var. P/Ni and Al/Ni ratios, var. reaction times; Product distribution;
参考文献
Cros, Philippe; Triantaphylides, Christian; Buono, Gerard
Journal of Organic Chemistry, 1988 , vol. 53, # 1 p. 185 - 187
反应条件
NiBr2(PPh3)2; triphenylphosphine in diethyl ether; benzene T=0°C; 0.5 h; Product distribution; Further Variations:CatalystsSolvents;
参考文献
Kamachi, Taku; Kuno, Akiko; Matsuno, Chikashi; Okamoto, Sentaro
Tetrahedron Letters, 2004 , vol. 45, # 24 p. 4677 - 4679
反应条件
tris(triphenylphosphine)ruthenium(II) chloride; air in benzene T=130°C; 48 h; other ruthenium complexes; Product distributionMechanism;
参考文献
Marciniec, Bogdan; Pietraszuk, Cezary; Foltynowicz, Zenon
Journal of Organometallic Chemistry, 1994 , vol. 474, # 1-2 p. 83 - 88
反应条件
sulfuric acid in pentane T=0°C; 0.5 h; further reagent trifluoroacetic acid;
参考文献
Meagher, Timothy P.; Shechter, Harold
Journal of Organic Chemistry, 1998 , vol. 63, # 13 p. 4193 - 4198
反应条件
1: 54 percent / sulfuric acid / pentane / 0.5 h / 0 °C / further reagent trifluoroacetic acid
2: 8 percent / cupric chloride, TDA-1 / various solvent(s) / 11 h / 120 - 124 °C
3: 92 percent / MCPBA / CH2Cl2 / 1.5 h / Ambient temperature
4: 91 percent / potassium hydroxide / H2O; tetrahydrofuran / 2 h
View Scheme
参考文献
Meagher, Timothy P.; Shechter, Harold
Journal of Organic Chemistry, 1998 , vol. 63, # 13 p. 4193 - 4198
