N,N'-((1S,2S)-cyclohexane-1,2-diyl)dipicolinamide; hexacarbonyl molybdenum in toluene
T=85°C;
参考文献
Palucki, Michael; Um, Joann M.; Conlon, David A.; Yasuda, Nobuyoshi; Hughes, David L.; Mao, Bing; Wang, Jian; Reider, Paul J.
Advanced Synthesis and Catalysis, 2001 , vol. 343, # 1 p. 46 - 50
sodium hydride; [(EtCN)3Mo(CO)3(EtCN)3]; (1R)-(-)-1,2-bis[2-pyridinylcarboxamido]-1-phenylethane in tetrahydrofuran
T=60°C; 4 h;
参考文献
Malkov, Andrei V.; Gouriou, Laure; Lloyd-Jones, Guy C.; Stary, Ivo; Langer, Vratislav; Spoor, Paul; Vinader, Victoria; Kocovsky, Pavel
Chemistry - A European Journal, 2006 , vol. 12, # 26 p. 6910 - 6929
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反应条件
N,N'-((1S,2S)-cyclohexane-1,2-diyl)dipicolinamide; hexacarbonyl molybdenum in toluene
T=85°C;
参考文献
Palucki, Michael; Um, Joann M.; Conlon, David A.; Yasuda, Nobuyoshi; Hughes, David L.; Mao, Bing; Wang, Jian; Reider, Paul J.
Advanced Synthesis and Catalysis, 2001 , vol. 343, # 1 p. 46 - 50
1: malonic acid dimethyl ester With sodium hydride in tetrahydrofuran
T=20°C; 0.333333 h;
2: 1-phenyl-1-(methoxycarbonyloxy)prop-2-ene With tetracarbonylbis(μ-chloro)dirhodium(I) in tetrahydrofuran
T=20°C; Further stages. Title compound not separated from byproducts.;
参考文献
Ashfeld, Brandon L.; Miller, Kenneth A.; Smith, Anna J.; Tran, Kristy; Martin, Stephen F.
Journal of Organic Chemistry, 2007 , vol. 72, # 24 p. 9018 - 9031
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
T=65°C; 3 h;
参考文献
Palucki, Michael; Um, Joann M.; Conlon, David A.; Yasuda, Nobuyoshi; Hughes, David L.; Mao, Bing; Wang, Jian; Reider, Paul J.
Advanced Synthesis and Catalysis, 2001 , vol. 343, # 1 p. 46 - 50
sodium hydride; (S)-(+)-1,2-bis(2-pyridinylcarboxamido)-3-methylbutane; [(EtCN)3Mo(CO)3(EtCN)3] in tetrahydrofuran
T=60°C; 12 h; Title compound not separated from byproducts;
参考文献
Malkov, Andrei V.; Gouriou, Laure; Lloyd-Jones, Guy C.; Stary, Ivo; Langer, Vratislav; Spoor, Paul; Vinader, Victoria; Kocovsky, Pavel
Chemistry - A European Journal, 2006 , vol. 12, # 26 p. 6910 - 6929
