(4-溴苯基乙炔基)三甲基硅烷合成路线 （共 34 条）
反应条件
1: NaOH / tetrahydrofuran; methanol / 1 h / 20 °C 2: 2.40 g / o-xylene / Heating View Scheme
参考文献
Setayesh; Grimsdale; Weil; Enkelmann; Muellen; Meghdadi; List; Leising
Journal of the American Chemical Society, 2001 , vol. 123, # 5 p. 946 - 953
反应条件
1: With sodium hydroxide in methanol; water Elimination; 2: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diethylamine Disproportionation; Further stages.;
参考文献
Mayoral, Maria Jose; Rest, Christina; Stepanenko, Vladimir; Schellheimer, Jennifer; Albuquerque, Rodrigo Q.; Fernandez, Gustavo
Journal of the American Chemical Society, 2013 , vol. 135, # 6 p. 2148 - 2151
反应条件
1: 60 percent / triphenylphosphine; Et3N; tetrakis(triphenylphosphine)palladium / toluene / 6 h / 110 °C
2: 71 percent / tetrabutylammonium fluoride / tetrahydrofuran / 0.67 h / 20 °C
View Scheme
参考文献
Onouchi; Maeda; Yashima
Journal of the American Chemical Society, 2001 , vol. 123, # 30 p. 7441 - 7442
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
Heating;
参考文献
Pena, Miguel A.; Perez Sestelo, Jose; Sarandeses, Luis A.
Synthesis, 2005 , # 3 art. no. Z14204SS, p. 485 - 492
反应条件
1.1: n-BuLi / diethyl ether
1.2: 90 percent / I2 / diethyl ether
2.1: CuI; Et3N / PdCl2(PPh3)2 / tetrahydrofuran
3.1: K2CO3 / methanol; CH2Cl2
4.1: 56 percent / CuI; Et3N / PdCl2(PPh3)2 / tetrahydrofuran / 12 h / 20 °C
View Scheme
参考文献
Li, Kun; Wang, Qing
Macromolecules, 2004 , vol. 37, # 4 p. 1172 - 1174
反应条件
aluminium trichloride in dichloromethane
T=0 - 20°C; 1 h;
参考文献
Schubert, Thomas; Hummel, Werner; Kula, Maria-Regina; Mueller, Michael
European Journal of Organic Chemistry, 2001 , # 22 p. 4181 - 4187
反应条件
1: (4-bromophenylethynyl)trimethylsilane With n-butyllithium
2: allyl(chloro)dimethylsilane
参考文献
Asao, Naoki; Tomeba, Hisamitsu; Yamamoto, Yoshinori
Tetrahedron Letters, 2005 , vol. 46, # 1 p. 27 - 30
反应条件
1: 93 percent / n-BuLi
2: 90 percent / KOH / H2O
View Scheme
参考文献
Asao, Naoki; Tomeba, Hisamitsu; Yamamoto, Yoshinori
Tetrahedron Letters, 2005 , vol. 46, # 1 p. 27 - 30
反应条件
1: 77 percent / n-BuLi
2: KOH / H2O
View Scheme
参考文献
Asao, Naoki; Tomeba, Hisamitsu; Yamamoto, Yoshinori
Tetrahedron Letters, 2005 , vol. 46, # 1 p. 27 - 30
反应条件
1,2,3-Benzotriazole; potassium phosphate; copper(l) iodide in dimethyl sulfoxide
T=120°C; 24 h; Inert atmosphere; optical yield given as percent deregioselective reaction;
参考文献
Joshi, Megha; Tiwari, Rakesh; Verma, Akhilesh Kumar
Organic Letters, 2012 , vol. 14, # 4 p. 1106 - 1109
