in diethyl ether under N2 a soln. of a mixt. of Ph3GeCl and Ph2GeCl2 was treated with an excess of LiAlH4; after hydrolysis the organic layer was dried over Na2SO4, pumped off, chromd. (silica gel, benzene/hexane);
参考文献
Cerveau, Genevieve; Colomer, Ernesto; Corriu, Robert J.P.; Young, J. Colin
Journal of Organometallic Chemistry, 1981 , vol. 205, # 1 p. 31 - 45
in neat (no solvent) byproducts: N2, ClCH2CO2CH2CH3; 1 equiv of diazoester adding slowly to an equimolar mixt. of Ge and Sn deriv. to result in an exothermic reaction with N2 evolution; allowing to stand for 24 h at 20°C; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 232, # 2 p. 137 - 146
