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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
甲磺酸苯酯
合成路线
(共 77 条)
16156-59-5
甲磺酸苯酯
→
反应条件
26209-45-0
反应条件
potassium phosphate; palladium diacetate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in water; tert-butyl alcohol T=110°C; Csp2-Csp3 Suzuki-Miyaura cross-coupling; 18 h; Inert atmosphereSealed tube;
参考文献
Molander, Gary A.; Beaumard, Floriane
Organic Letters, 2011 , vol. 13, # 5 p. 1242 - 1245
16156-59-5
甲磺酸苯酯
+
94839-07-3
3.4-(亚甲基二氧基)苯硼酸
→
反应条件
24382-05-6
反应条件
potassium phosphate; 1-methyl-2-(2-(dicyclohexylphosphino)phenyl)-1H-benzoimidazole; palladium diacetate in tert-butyl alcohol T=20 - 120°C; Suzuki-Miyaura coupling; 24 h;
参考文献
Chung, Kin Ho; So, Chau Ming; Wong, Shun Man; Luk, Chi Him; Zhou, Zhongyuan; Lau, Chak Po; Kwong, Fuk Yee
Chemical Communications, 2012 , vol. 48, # 14 p. 1967 - 1969
55552-70-0
3-呋喃硼酸
+
16156-59-5
甲磺酸苯酯
→
反应条件
13679-41-9
3-苯基呋喃
反应条件
potassium phosphate; 1-methyl-2-(2-(dicyclohexylphosphino)phenyl)-1H-benzoimidazole; palladium diacetate in tert-butyl alcohol T=20 - 120°C; Suzuki-Miyaura coupling; 24 h;
参考文献
Chung, Kin Ho; So, Chau Ming; Wong, Shun Man; Luk, Chi Him; Zhou, Zhongyuan; Lau, Chak Po; Kwong, Fuk Yee
Chemical Communications, 2012 , vol. 48, # 14 p. 1967 - 1969
→
反应条件
1666-96-2
反应条件
[Ni0(1,5-cyclooctadiene)2]; potassium phosphate; PCy3∙HBF4 in water; tert-butyl alcohol T=110°C; Suzuki-Miyaura cross coupling; 4 h; Inert atmosphere;
参考文献
Molander, Gary A.; Beaumard, Floriane
Organic Letters, 2010 , vol. 12, # 18 p. 4022 - 4025
16156-59-5
甲磺酸苯酯
→
反应条件
7155-37-5
反应条件
sulfuric acid; potassium nitrate
参考文献
Schall
Journal fuer Praktische Chemie (Leipzig), 1893 , vol. <2> 48, p. 243
16156-59-5
甲磺酸苯酯
+
3989-14-8
→
反应条件
7380-78-1
反应条件
copper(l) iodide; [PdCl2(2,2'-bipyridine)]; cyclohexyl BrettPhos in N,N-dimethyl-formamide T=150°C; 24 h;
参考文献
Nishihara, Yasushi; Ogawa, Daisuke; Noyori, Shintaro; Iwasaki, Masayuki
Chemistry Letters, 2012 , vol. 41, # 11 p. 1503 - 1505
10531-78-9
+
16156-59-5
甲磺酸苯酯
→
反应条件
7420-86-2
反应条件
1: With CM-phos; palladium diacetate; potassium carbonate; triethylamine Inert atmosphere; 2: in N,N-dimethyl-formamide; tert-butyl alcohol T=110°C; 24 h; Inert atmosphere;
参考文献
So, Chau Ming; Lau, Chak Po; Kwong, Fuk Yee
Chemistry - A European Journal, 2011 , vol. 17, # 3 p. 761 - 765
110-43-0
+
16156-59-5
甲磺酸苯酯
→
反应条件
54929-04-3
+
6683-94-9
反应条件
potassium phosphate; [Pd(η3-1-Ph-allyl)(μ-Cl)]2; (Mor-DalPhos) in 1,4-dioxane; tert-butyl alcohol T=90°C; Inert atmosphereGlovebox;
参考文献
Alsabeh, Pamela G.; Stradiotto, Mark
Angewandte Chemie - International Edition, 2013 , vol. 52, # 28 p. 7242 - 7246
Angew. Chem., 2013 , vol. 125, # 28 p. 7383 - 7387
16156-59-5
甲磺酸苯酯
→
反应条件
68574-35-6
反应条件
bromine
参考文献
Schall
Journal fuer Praktische Chemie (Leipzig), 1893 , vol. <2> 48, p. 243
16156-59-5
甲磺酸苯酯
+
15754-51-5
→
反应条件
799-55-3
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; 1,1'-bis(diphenylphosphanyl)ferrocenenickel(II) chloride; N-ethyl-N,N-diisopropylamine; zinc in N,N-dimethyl-formamide T=100°C; 36 h; Inert atmosphere;
参考文献
Shen, Chaoren; Yang, Guoqiang; Zhang, Wanbin
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 17 p. 3500 - 3505
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