2-甲基-1-苯基-1H-吲哚合成路线 （共 20 条）
反应条件
tris(dibenzylideneacetone)dipalladium (0); sodium t-butanolate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in 1,4-dioxane
T=110°C; 14 h; Inert atmosphere;
参考文献
Barluenga, Jose; Jimenez-Aquino, Agustin; Aznar, Fernando; Valdes, Carlos
Journal of the American Chemical Society, 2009 , vol. 131, p. 4031 - 4041
反应条件
sodium t-butanolate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; tris-(dibenzylideneacetone)dipalladium(0) in 1,4-dioxane
T=50 - 90°C; 17 h;
参考文献
Barluenga, Jose; Jimenez-Aquino, Agustin; Valdes, Carlos; Aznar, Fernando
Angewandte Chemie - International Edition, 2007 , vol. 46, # 9 p. 1529 - 1532
反应条件
copper(l) iodide; (1R,2R)-(-)-trans-1,2-diaminocyclohexane; potassium carbonate in water
T=80°C; Buchwald N-arylation; 18 h;
参考文献
Swapna, Kokkirala; Murthy, Sabbavarapu Narayana; Nageswar, Yadavalli Venkata Durga
European Journal of Organic Chemistry, 2010 , # 34 p. 6678 - 6684
反应条件
dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0) in toluene
T=80°C; 4 h;
参考文献
Willis, Michael C.; Brace, Gareth N.; Findlay, Thomas J. K.; Holmes, Ian P.
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 7-8 p. 851 - 856
反应条件
copper(l) iodide; (1R,2R)-(-)-trans-1,2-diaminocyclohexane; potassium carbonate in water
T=100°C; Buchwald N-arylation; 18 h;
参考文献
Swapna, Kokkirala; Murthy, Sabbavarapu Narayana; Nageswar, Yadavalli Venkata Durga
European Journal of Organic Chemistry, 2010 , # 34 p. 6678 - 6684
反应条件
C22H26Cl2NPPd; sodium t-butanolate in toluene
T=110°C; 22 h; Inert atmosphere;
参考文献
Samblanet, Danielle C.; Schmidt, Joseph A. R.
Journal of Organometallic Chemistry, 2012 , vol. 720, p. 7 - 18,12
反应条件
potassium tert-butylate; bis(dibenzylideneacetone)-palladium(0); biphenyl-2-yl-di-tert-butyl-phosphane in toluene
0.4 h; Inert atmosphereReflux; Reagent/catalyst;
参考文献
Liu, Bingxin; Hong, Xiaohu; Yan, Dong; Xu, Shuguang; Huang, Xiaomei; Xu, Bin
Organic Letters, 2012 , vol. 14, # 17 p. 4398 - 4401
反应条件
potassium tert-butylate in toluene
0.25 h; Heating;
参考文献
Corre, M. Le; Hercouet, A.; Stanc, Y. Le; Baron, H. Le
Tetrahedron, 1985 , vol. 41, # 22 p. 5313 - 5320
反应条件
copper(l) iodide; K3PO4 in N,N-dimethyl-formamide
T=110°C; Inert atmosphere; Reagent/catalystSolvent;
参考文献
Besandre, Ronald; Jaimes, Miguel; May, Jeremy A.
Organic Letters, 2013 , vol. 15, # 7 p. 1666 - 1669
反应条件
copper(l) iodide; K3PO4 in 1,4-dioxane
T=90°C; 16 h; Inert atmosphere;
参考文献
Besandre, Ronald; Jaimes, Miguel; May, Jeremy A.
Organic Letters, 2013 , vol. 15, # 7 p. 1666 - 1669
