2-甲基-1-苯基-1H-吲哚合成路线 （共 20 条）
反应条件
sodium methylate in toluene
Heating;
参考文献
Corre, Maurice Le; Hercouet, Alain; Baron, Henri Le
Journal of the Chemical Society, Chemical Communications, 1981 , # 1 p. 14 - 15
反应条件
PPA
T=85 - 115°C; 150 h;
参考文献
Tokmakov, Gennadii P.; Grandberg, Igor I.
Tetrahedron, 1995 , vol. 51, # 7 p. 2091 - 2098
反应条件
1: toluene-4-sulfonic acid / benzene / |Dean-Stark; |Inert atmosphere; |Reflux
2: copper(l) iodide; K3PO4 / 1,4-dioxane / 16 h / 90 °C / |Inert atmosphere
View Scheme
参考文献
Besandre, Ronald; Jaimes, Miguel; May, Jeremy A.
Organic Letters, 2013 , vol. 15, # 7 p. 1666 - 1669
反应条件
1: toluene-4-sulfonic acid / benzene / |Dean-Stark; |Inert atmosphere; |Reflux
2: copper(l) iodide; K3PO4 / N,N-dimethyl-formamide / 110 °C / |Inert atmosphere
View Scheme
参考文献
Besandre, Ronald; Jaimes, Miguel; May, Jeremy A.
Organic Letters, 2013 , vol. 15, # 7 p. 1666 - 1669
反应条件
1: toluene-4-sulfonic acid / benzene / |Dean-Stark; |Inert atmosphere; |Reflux
2: copper(l) iodide; K3PO4 / 1,4-dioxane / 16 h / 90 °C / |Inert atmosphere
View Scheme
参考文献
Besandre, Ronald; Jaimes, Miguel; May, Jeremy A.
Organic Letters, 2013 , vol. 15, # 7 p. 1666 - 1669
反应条件
1: 76 percent
2: NEt3 / CH2Cl2; toluene
3: 80 percent / MeONa / toluene / Heating
View Scheme
参考文献
Corre, Maurice Le; Hercouet, Alain; Baron, Henri Le
Journal of the Chemical Society, Chemical Communications, 1981 , # 1 p. 14 - 15
反应条件
1: NEt3 / CH2Cl2; toluene
2: 80 percent / MeONa / toluene / Heating
View Scheme
参考文献
Corre, Maurice Le; Hercouet, Alain; Baron, Henri Le
Journal of the Chemical Society, Chemical Communications, 1981 , # 1 p. 14 - 15
反应条件
in acetonitrile
1 h; Irradiation;
参考文献
Moran, Ricardo J.; Cramer, Christopher; Falvey, Daniel E.
Journal of Organic Chemistry, 1997 , vol. 62, # 9 p. 2742 - 2751
反应条件
air; sodium hydride
1.) DMF, 0 deg C, 5 min; 0 deg C, 0.5 h, 2.) CH2Cl2, hν; Yield given. Multistep reaction;
参考文献
Maiorana, Stefano; Baldoli, Clara; Del Buttero, Paola; Di Ciolo, Michela; Papagni, Antonio
Synthesis, 1998 , # 5 p. 735 - 738
反应条件
acetic acid; zinc(II) chloride
参考文献
Mann; Haworth
Journal of the Chemical Society, 1944 , p. 670,675
