triphenylphosphine; Pd-Gr in tetrahydrofuran; water 0.5 h; Heatingother allylic esters; other palladium catalysts; other solvents; also diethyl malonate and 1-(1-cyclohexen-1-yl)pyrrolidine as nucleophiles; Product distributionMechanism;
参考文献
Journal of Organometallic Chemistry, , vol. 268, # 1 p. 97 - 106
1: N-benzoyl-N-benzylbenzenesulfonamide With 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in toluene Desulfonylation; Heating; 2: allyl bromide With dimethylpropylene urea in toluene Alkylation; Heating;