1: trans-2-buten-1-ol With caesium carbonate in water T=20°C; Heck reaction; 0.25 h; 2: iodobenzene With Kaiser oxime-derived complex on resin base in water T=120°C; Heck reaction; 14 h; Further stages. Title compound not separated from byproducts.;
参考文献
Advanced Synthesis and Catalysis, , vol. 349, # 17-18 p. 2572 - 2584
1: With chloro-trimethyl-silane; copper(I) thiophene-2-carboxylate; (R)-p-tol-BINAP in diethyl ether T=-78°C; Inert atmosphere; 2: With hydrogenchloride in methanol; diethyl ether; water Inert atmosphere;
