dichloro(2-pyridinecarboxylato)gold in dichloromethane
T=0°C; 1 h;
参考文献
McGonigal, Paul R.; De Leon, Claudia; Wang, Yahui; Homs, Anna; Solorio-Alvarado, Cesar R.; Echavarren, Antonio M.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 52 p. 13093 - 13096
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / |Inert atmosphere
1.2: 12 h / 23 °C / |Inert atmosphere
2.1: [MeCNAu((1,1′-biphenyl-2-yl)-di-tert-butylphosphine)]+SbF6− / 1,2-dichloro-ethane / 3 h / 120 °C / |Sealed tube; |Inert atmosphere
View Scheme
参考文献
Wang, Yahui; McGonigal, Paul R.; Herle, Bart; Besora, Maria; Echavarren, Antonio M.
Journal of the American Chemical Society, 2014 , vol. 136, # 2 p. 801 - 809
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.67 h / -78 °C / |Inert atmosphere
1.2: 5 h / 20 °C / |Inert atmosphere
2.1: dichloro(2-pyridinecarboxylato)gold / dichloromethane / 1 h / 0 °C
View Scheme
参考文献
McGonigal, Paul R.; De Leon, Claudia; Wang, Yahui; Homs, Anna; Solorio-Alvarado, Cesar R.; Echavarren, Antonio M.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 52 p. 13093 - 13096
