6-甲基-4-苯基香豆素合成路线 （共 47 条）
反应条件
N,N-dicyclohexylmethylamine; tetraethylammonium chloride; palladium diacetate in N,N-dimethyl acetamide T=95°C; Heck reaction; 48 h;
参考文献
CONSIGLIO NAZIONALE DELLE RICERCHE; PICCOLO, Oreste
Patent: WO2005/5356 A2, 2005 ;
Location in patent: Page/Page column 8; 9 ;
反应条件
potassium phosphate; bis(1,5-cyclooctadiene)nickel (0); tri-cyclo-hexyl-phosphine in tetrahydrofuran T=20°C; Suzuki-Miyaura cross-coupling; 4 h;
参考文献
Tang, Zhen-Yu; Hu, Qiao-Sheng
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1635 - 1637
反应条件
trifluoroacetic acid; palladium diacetate in dichloromethane T=20°C; Cyclization; intramolecular hydroarylation; 10 h;
参考文献
Jia, Chengguo; Piao, Dongguo; Kitamura, Tsugio; Fujiwara, Yuzo
Journal of Organic Chemistry, 2000 , vol. 65, # 22 p. 7516 - 7522
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone in 1,4-dioxane T=110°C; 12 h;
参考文献
Jagdale, Arun R.; Sudalai, Arumugam
Tetrahedron Letters, 2008 , vol. 49, # 23 p. 3790 - 3793
反应条件
palladium diacetate; caesium carbonate in diethylene glycol dimethyl ether T=100°C; P=760.051 Torr; 12 h; Inert atmosphere;
参考文献
Sasano, Kota; Takaya, Jun; Iwasawa, Nobuharu
Journal of the American Chemical Society, 2013 , vol. 135, # 30 p. 10954 - 10957
反应条件
bis-triphenylphosphine-palladium(II) chloride; potassium phosphate in N,N-dimethyl acetamide T=90°C; 2 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Venkatesh, Varadhachari; Jadhav, Deepak N.
European Journal of Organic Chemistry, 2010 , # 20 p. 3945 - 3955
反应条件
1: With palladium diacetate; calcium carbonate in methanol T=60°C; 4 h; 2: With hydrogen in methanol T=20°C;
参考文献
Barancelli, Daniela A.; Salles, Airton G.; Taylor, Jason G.; Correia, Carlos Roque D.
Organic Letters, 2012 , vol. 14, # 23 p. 6036 - 6039
反应条件
sodium carbonate; p-toluenesulfonyl chloride; palladium dichloride in tetrahydrofuran; water T=60°C;
参考文献
Luo, Yong; Wu, Jie
Tetrahedron Letters, 2009 , vol. 50, # 18 p. 2103 - 2105
反应条件
palladium diacetate in tetrahydrofuran T=20°C; Inert atmosphere;
参考文献
Gao, Wei; Luo, Yong; Ding, Qiuping; Peng, Yiyuan; Wu, Jie
Tetrahedron Letters, 2010 , vol. 51, # 1 p. 136 - 138
反应条件
bis-triphenylphosphine-palladium(II) chloride; potassium phosphate in N,N-dimethyl acetamide T=90°C; 2 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Venkatesh, Varadhachari; Jadhav, Deepak N.
European Journal of Organic Chemistry, 2010 , # 20 p. 3945 - 3955
