in neat (no solvent) byproducts: propene, butene, hexene; hydride condensed onto palladium complex at 77 K and warmed slowly to room temp.; volatile products separated by trap-to-trap fractional distillation at 298 K, 253 K, 153 K and 77 K, fractions collected at each temp. dissolved in ether and solns. passed through gas chromatograph;
参考文献
Ssebuwufu, P. John; Glockling, F.; Harriott, P.
Inorganica Chimica Acta, 1985 , vol. 98, p. L35 - L38
Ansari, S.; Grobe, J.
Z. Naturforsch. b, 1975 , vol. 30, p. 531 - 534
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Gmelin Handbook: F: PerFHalOrg.SVol.1, 5.3.6, page 174 - 175
in benzene Irradiation (UV/VIS); Equimolar mixture of Me3SnH and vinyldiphenylphosphine compound in a quartz Schlenk tube is irradiated under Ar for 12 h (high-pressure mercury lamp).; distn. under reduced pressure;
参考文献
Mitchell, Terence N.; Belt, Heinz-Joachim
Journal of Organometallic Chemistry, 1989 , vol. 368, p. 167 - 172
in neat (no solvent) React. (vac. line, no solvent) at room temp. for 10 min.; Removal of Me3SnCl by passing the mixt. through a trap cooled to -95°C (toluene). IR and NMR spectra indicate presence of resulting compounds in approximately equimolar amt.;
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2886 - 2888
