in neat (no solvent)
equimolar amts. of Me3SnH and SiF2Cl2 room temp., 3.5 days; removing of Me3SnBr by trap coolingto -131°C, cooling to -196°C; not isolated; IR, (1)H-, (19)F-NMR spectroscopy (identified 5percent SiF3H, 5percent SiH4 and 5percent SiFCl2H in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent)
N2 atmosphere, high vac. line; condensing (molar ratio SnMe3H:Si2HF5:C2F4 1:1:3), warming (room temp., 1.5 h); passing through traps (-78°C and -46°C);
参考文献
D'Errico, John; Sharp, Kenneth G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 1879 - 1882
2,2'-azo-bisisobutyronitrile in neat (no solvent)
under protective gas addn. of AIBN to the mixt. of (CH3)3SnH and P(C6H5)2CHCH2 without solvent slowly heating to 60-70°C, then 6-7 h at 70-90°C meanwhile addn. of the rest of AIBN; vac. distn., elem. anal.;
参考文献
Weichmann, H.; Quell, G.; Tzschach, A.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1980 , vol. 462, p. 7 - 17
