catalyst: azobisisobutyronitrile in neat (no solvent)
Irradiation (UV/VIS); equimolar amts. of alkyne and Me3SnH was irradiated with UV light (Hg high pressure lamp) under Ar in the presence of a catalytic amt. of AIBN for 11 h (IR and (1)H NMR monitoring); t-BuCH=C(SnMe3)2 to t-Bu(Me3Sn)C=CHSnMe3 ratio 98:2, total yield 34percent; the reaction mixt. was distilled under reduced pressure (b.p. 59°C/0.01 mm Hg); elem. anal. for the isomeric mixt., isomers were not sepd.;
参考文献
Mitchell, T.N.; Amamria, A.
Journal of Organometallic Chemistry, 1983 , vol. 252, # 1 p. 47 - 56
catalyst: azobisisobutyronitrile in neat (no solvent)
equimolar amts. of the alkyne and Me3SnH were heated at 70°C under Ar in the presence of a catalytic amt. of AIBN for 3-4 h (IR and (1)H NMR monitoring); PhCH=C(SnMe3)2 to Ph(Me3Sn)C=CHSnMe3 ratio 95:5, total yield 81percent; the reaction mixt. was distilled under reduced pressure (b.p. 86°C/0.005 mm Hg); elem. anal. for the isomeric mixt., isomers were not sepd.;
参考文献
Mitchell, T.N.; Amamria, A.
Journal of Organometallic Chemistry, 1983 , vol. 252, # 1 p. 47 - 56
catalyst: azobisisobutyronitrile in neat (no solvent)
equimolar amts. of the alkyne and Me3SnH were heated at 70°C under Ar in the presence of a catalytic amt. of AIBN for 3-4 h (IR and (1)H NMR monitoring); MeOCH2CH=C(SnMe3)2 to MeOCH2(Me3Sn)C=CHSnMe3 ratio 59:41, total yield 58percent; the reaction mixt. was distilled under reduced pressure (b.p. 60°C/0.02 mm Hg); elem. anal. for the isomeric mixt., isomers were not sepd.;
参考文献
Mitchell, T.N.; Amamria, A.
Journal of Organometallic Chemistry, 1983 , vol. 252, # 1 p. 47 - 56
catalyst: azobisisobutyronitrile in neat (no solvent)
equimolar amts. of the alkyne and Me3SnH were heated at 70°C under Ar in the presence of a catalytic amt. of AIBN for 3-4 h (IR and (1)H NMR monitoring); PhOCH2CH=C(SnMe3)2 to PhOCH2(Me3Sn)C=CHSnMe3 ratio 61:39, total yield 57percent; the reaction mixt. was distilled under reduced pressure (b.p. 102°C/0.03 mm Hg); elem. anal. for the isomeric mixt., isomers were not sepd.;
参考文献
Mitchell, T.N.; Amamria, A.
Journal of Organometallic Chemistry, 1983 , vol. 252, # 1 p. 47 - 56
in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temperature, two equiv. of tinhydride, reactn. time 2 h; not isolated; IR spectroscopy (identified 35-40percent SiCl3H, 40percent SiH4 and 10percent SiCl2HBr in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
