in neat (no solvent) Warming of starting materials (in absence of solvent, vac. line) for 30 min to room temp.; Removal of Me3SnBr by passing the mixt. through a trap cooled to -95°C (toluene), IR and NMR identification of volatile resulting compd.;
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2886 - 2888
in neat (no solvent) React. (vac. line, no solvent) at room temp. for 10 min.; Removal of Me3SnCl by passing the mixt. through a trap cooled to -95°C (toluene). IR and NMR spectra indicate presence of resulting compounds in approximately equimolar amt.;
in neat (no solvent) React. of equimolar amt. of starting materials (vac. line, room temp., 10 min).; Removal of Me3SnCl by passing the mixt. through a trap cooled to -95°C (toluene). IR identificatio of resulting compounds.;
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2886 - 2888
Carlson, D. J.; Ingold, K. U.
Journal of the American Chemical Society, 1968 , vol. 90, p. 7047 - 7055
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.1.4.4, page 15 - 16
in neat (no solvent) Warming mixt. of equimolar amt. of starting materials (condensed at -196°C) to -80°C (30 min) and then gradually to 10°C.; Removal of Me3SnCl by passing the mixt. through a trap cooled to -95°C (toluene). NMR spectrum indicate presence of major resulting compounds, with small amt. of SiF3SiHBr2 and unreacted SiF3SiFHBr.;
in neat (no solvent) React. of equimolar amt. of starting materials (vac. line, room temp., 10 min).; Removal of Me3SnCl by passing the mixt. through a trap cooled to -95°C (toluene). IR identificatio of resulting compounds.;
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2886 - 2888
Bullpitt, M. L.; Kitching, W.
Journal of Organometallic Chemistry, 1972 , vol. 46, p. 21 - 29
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Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.1.4.4, page 15 - 16
