Bullpitt, M. L.; Kitching, W.
Journal of Organometallic Chemistry, 1972 , vol. 46, p. 21 - 29
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Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.1.4.4, page 15 - 16
in neat (no solvent) equimolar amts. of Me3SnH and SiF2Br2 room temp., 12 h; removing Me3SnBr by trap (pentane) cooling to -131°C, cooling to -196°C; not isolated; Ir, (1)H- and (19)F-NMR spectroscopy (identified 90percent SiF2HBr in product mixt.);
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D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 6-8 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
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D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, two equiv. of tinhydride, reactn. time 2 h; not isolated; IR spectroscopy (identified 35-40percent SiCl3H, 40percent SiH4 and 10percent SiCl2HBr in product mixt.);
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D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 0.25 h; not isolated; IR spectroscopy (identified 20percent SiBr3H and 20percent SiH4 in product mixt.);
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D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent) equimolar amts. of Me3SnH and SiF2Cl2 room temp., 3.5 days; removing of Me3SnBr by trap coolingto -131°C, cooling to -196°C; not isolated; IR, (1)H-, (19)F-NMR spectroscopy (identified 5percent SiF3H, 5percent SiH4 and 5percent SiFCl2H in product mixt.);
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D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent) N2 atmosphere, high vac. line; condensing (molar ratio SnMe3H:Si2HF5:C2F4 1:1:3), warming (room temp., 1.5 h); passing through traps (-78°C and -46°C);
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Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1879 - 1882
in neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 3 h; not isolated; IR spectroscopy (identified 85percent SiCl3H, 5percent SiH4 and 5percent SiCl4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
