in tetrahydrofuran LiSnMe3 added to PhGeMe3 in THF, stirred at 24°C for 1 h or 50°C for 30 min, hydrolysis with water; org. layer extd. with ether, dried over Na2SO4; products isolated by preparative by GLC;
参考文献
Mochida, Kunio
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 9 p. 3299 - 3306
acetic acid in acetic acid Kinetics; stannane was added to AcOH in a NMR tube, mixt. was kept for 20 d, reaction followed by (1)H NMR spectroscopy; ca. 29percent of the substrate was consumed, rate const. for the initial 5-10percent reaction (first 2 d) when only Me3SnOAc and Me3GeOAc were formed; not isolated, identified by (1)H NMR spectrum;
参考文献
Cuthberston, Matthew J.; Hawker, Darryl W.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 7 - 24
hydrogenchloride in methanol Kinetics; 8.5 M aq. HCl was added to a methanol soln. of the stannane in a NMR tube, reaction was followed by (1)H NMR spectroscopy for 50 h; 70percent of the substrate has been consumed, rate consts. according to different reaction paths are given; further products; not isolated, identified by (1)H NMR spectrum;
参考文献
Cuthberston, Matthew J.; Hawker, Darryl W.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 7 - 24
hydrogenchloride in methanol Kinetics; 8.5 M aq. HCl was added to a methanol soln. of the stannane in a NMR tube, reaction was followed by (1)H NMR spectroscopy for 50 h; 70percent of the substrate has been consumed, rate consts. according to different reaction paths are given; further products; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 7 - 24
in methanol Kinetics; a mixt. of 0.197 M Me3GeSnMe3 and 0.194 M Me2SnCl2 in methanol was keptfor 160 min, reaction was followed by (1)H NMR spectroscopy; second order kinetics, rate const. is given; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 25 - 38
in methanol a mixt. of Me3GeSnMe3 and Me2SnCl2 in methanol was kept for 7 h, reaction was followed by (1)H NMR spectroscopy; most of the reactants have been consumed, Me3GeSnMe2Cl and Me2SnHCl were not found, "dimethyltin polymer" was also present; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 25 - 38
in methanol a mixt. of Me3GeSnMe3 and (CD3)3SnCl in methanol was kept for 15 h, reaction was followed by (1)H NMR spectroscopy; Me3SnCl:Me2(CD3)SnCl:Me(CD3)2SnCl=1:1:1.5, Me4Sn:Me3SnCD3:Me2Sn(CD3)2:MeSn(CD3)3=1:1.5:3.4:10; further products; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 25 - 38
acetic acid in acetic acid Kinetics; stannane was added to AcOH in a NMR tube, mixt. was kept for 20 d, reaction followed by (1)H NMR spectroscopy; ca. 29percent of the substrate was consumed, rate const. for the initial 5-10percent reaction (first 2 d) when only Me3SnOAc and Me3GeOAc were formed; not isolated, identified by (1)H NMR spectrum;
参考文献
Cuthberston, Matthew J.; Hawker, Darryl W.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 7 - 24
