1: With water; triphenylphosphine; tris-(dibenzylideneacetone)dipalladium(0) in tetrahydrofuran T=140°C; 0.25 h; 2: With lithium aluminium tetrahydride in tetrahydrofuran T=120°C; 3: With hydrogen iodide in water T=120°C; 0.166667 h;
参考文献
Eriksson, Jonas; Antoni, Gunnar; Langstroem, Bengt
Journal of Labelled Compounds and Radiopharmaceuticals, 2004 , vol. 47, # 11 p. 723 - 731
Kirillova, Marina V.; Da Silva, Jose A. L.; Da Silva, Joao J. R. Frausto; Palavra, Antonio F.; Pombeiro, Armando J. L.
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 10 p. 1765 - 1774
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反应条件
in dichloromethane-d2 Irradiation (UV/VIS); Irradiation of complex at 350-380 nm under 20 atm of CO in CD2Cl2 at 6-8°C;;
参考文献
Goldberg, Karen I.; Bergman, Robert G.
Organometallics, 1987 , vol. 6, p. 430 - 432
in tetrahydrofuran THF soln. of Fe3(CO)12 was stirred under 1 atm of (13)CO at room temp. for 8 h in the dark; no measurable (13)CO-(12)CO exchange in the absence of hydride promotor, less than a 1percent loss of Fe3(CO)12 (forming Fe(CO)5); mass and IR spectral data;
参考文献
Bricker, Jeffery C.; Payne, Martin W.; Shore, Sheldon G.
Organometallics, 1987 , vol. 6, p. 2545 - 2547
in chloroform-d1 stirring HFeCo3(CO12 in CDCl3 for 4 days in sealed tube at room temp. in presence of <1 atm of (13)CO; evapd. in vac., chromd. (SiO2, CHCl3);
参考文献
Aime, Silvio; Osella, Domenico; Gobetto, Roberto; Johnson, Brian F. G.; Milone, Luciano
Inorganica Chimica Acta, 1983 , vol. 68, p. 141 - 146
CH2Cl2 in dichloromethane byproducts: (13)CO2; dissolving Au complex in CH2Cl2; passing stream of CO through soln. for30 min; sealing vessel; mechanism discussed;;
参考文献
Bos, W.; Bour, J. J.; Steggerda, J. J.; Pignolet, L. H.
Inorganic Chemistry, 1985 , vol. 24, p. 4298 - 4301
in methanol; dichloromethane A soln. of tungsten complex in CH2Cl2/MeOH (9/1) is stirred in (13)CO-atmosphere (1 bar) for 2.5 h at -20°C, the part of (13)C containing ester decreases with increasing reaction time.; reducing of soln. under vac., sepn. by thin layer chromy. on silica gel, ester is eluted (CH2Cl2), MS-anal., isotopic compound (ester) contains 44-87 percent (13)C;
参考文献
Fischer, Helmut; Jungklaus, Holger; Schmid, Johann
Journal of Organometallic Chemistry, 1989 , vol. 368, p. 193 - 198
