in neat (no solvent) react. between (15)NO and (13)CO at 480-800 °C on Pd(110); angular-resolved temperature programmed desorption and quadrupole mass spectrometry;
参考文献
Ma, Yunsheng; Rzeznicka, Izabela; Matsushima, Tatsuo
Chemical Physics Letters, 2004 , vol. 388, # 1-3 p. 201 - 207
in neat (no solvent) desorption of CO (adsorbed on reduced Rh/ SiO2 catalyst) at 473-810 K; mass sp.;
参考文献
Shanmugam, Muralidharan; Wilcoxen, Jarett; Habel-Rodriguez, Diana; Cutsail Iii, George E.; Kirk, Martin L.; Hoffman, Brian M.; Hille, Russ
Journal of the American Chemical Society, 2013 , vol. 135, # 47 p. 17775 - 17782
catalyst:5percentPt/γ-Al2O3 in neat (no solvent) Kinetics; 0.5percentFe-5percentPt/γ-Al2O3 as catalyst, 90 °C 1.8 atm, 45percentH2, 1percentO2, 1percentCO and 53 percent He;
参考文献
Sirijaruphan, Amornmart; Goodwin Jr., James G.; Rice, Richard W.
Journal of Catalysis, 2004 , vol. 224, # 2 p. 304 - 313
rhodium in neat (no solvent) gas mixt. (13CO:14NO = 1:1, P = 7.5E-5 Torr) introduced in react. chamber with Rh(110) catalyst (300-900 K); LEED, XPS, QMS;
catalyst: Pd/Al2O3 in water; acetic acid PVMo-contg. compd. (5E-6 mol) was dissolved in 9:1 AcOH/H2O; addn. of CO(2 bar) at 90°C for 5 h in the presence of 5percent Pd/Al2O3; (13)C NMR studies at 125 ppm;
