1,3,3,3-四氟-1-丙烯合成路线 （共 43 条）
反应条件
Aliquatreg; 336; potassium hydroxide in water
T=50 - 55°C; 6 h; Autoclave; TimeTemperatureReagent/catalyst;
参考文献
HONEYWELL INTERNATIONAL INC.; Nair, Haridasan K.; Singh, Rajiv Ratna; Poss, Andrew Joseph; Nalewajek, David
Patent: US2013/211156 A1, 2013 ;
Location in patent: Paragraph 0028; 0029 ;
反应条件
hydrogen fluoride; SbF5
T=120 - 121°C; P=9551.8 - 29721.1 Torr; 3.5 h; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US2007/118003 A1, 2007 ;
Location in patent: Page/Page column 4-5 ;
反应条件
potassium hydroxide in anhydrous butyl ether
参考文献
Knunyants,I.L. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1960 , p. 1312 - 1317
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1960 , p. 1412 - 1418
反应条件
hydrogen fluoride; SbF5
T=120 - 121°C; P=9551.8 - 29721.1 Torr; 3.5 h; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US2007/118003 A1, 2007 ;
Location in patent: Page/Page column 4-5 ;
反应条件
hydrogen fluoride; Catalyst M-Chromium oxide
T=300°C;
参考文献
Honeywell International, Inc.
Patent: US2005/90698 A1, 2005 ;
Location in patent: Page/Page column 5 ;
反应条件
hydrogen fluoride
T=80°C; P=775.743 Torr; 0.00127778 - 0.00761111 h; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US2005/20862 A1, 2005 ;
Location in patent: Page 3; 4 ;
反应条件
carbon
T=525°C; 0.00555556 - 0.00833333 h; Product distribution / selectivity;
参考文献
HONEYWELL INTERNATIONAL, INC.
Patent: WO2005/108334 A1, 2005 ;
Location in patent: Page/Page column 8; 12-13 ;
反应条件
hydrogen fluoride
T=200 - 500°C; 0.00138889 - 0.00555556 h;
参考文献
HONEYWELL INTERNATIONAL INC.; Nair, Haridasan K.; Singh, Rajiv Ratna; Poss, Andrew Joseph; Nalewajek, David
Patent: US2013/211156 A1, 2013 ;
Location in patent: Paragraph 0035 ;
反应条件
hydrogen fluoride; fluorinated chrome oxide
T=365°C; P=750.075 Torr; 6 h; Product distribution / selectivity;
参考文献
Komatsu, Yuzo; Karube, Daisuke
Patent: US2012/302802 A1, 2012 ;
Location in patent: Page/Page column 4 ;
反应条件
hydrogen fluoride; oxygen
T=350°C; 0.3 h; Reagent/catalystTime; Overall yield = 94 percentChromat.; chemoselective reaction;
参考文献
DAIKIN INDUSTRIES, LTD.; KARUBE, Daisuke; CHAKI, Takehiro; NISHIUMI, Masami; SHIBANUMA, Takashi; ARAI, Masashi
Patent: WO2013/111911 A1, 2013 ;
Location in patent: Page/Page column 29 ;
