4,7-二(噻吩-2-基)苯并[c][1,2,5]噻二唑合成路线 （共 14 条）
参考文献
Zhao, Xiaoyong; Piliego, Claudia; Kim, Bongsoo; Poulsen, Daniel A.; Ma, Biwu; Unruh, David A.; Frechet, Jean M. J.
Chemistry of Materials, 2010 , vol. 22, # 7 p. 2325 - 2332
反应条件
N-bromosuccinmide in N,N-dimethyl-formamide T=20°C; 0.25 h;
参考文献
Li, Yilin; Scudiero, Louis; Ren, Tianhui; Dong, Wen-Ji
Journal of Photochemistry and Photobiology A: Chemistry, 2012 , vol. 231, # 1 p. 51 - 59
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether; ethanol; water
Inert atmosphereReflux;
参考文献
Chen, Ming; Haeussler, Matthias; Moad, Graeme; Rizzardo, Ezio
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 17 p. 6111 - 6119
反应条件
1: With palladium diacetate; triphenylphosphine in tetrahydrofuran
T=20°C; Negishi Coupling Reaction; 1.58333 h;
2: With hydrogenchloride in tetrahydrofuran; water
T=20°C; 0.5 h;
参考文献
Zhang, Chunming
Patent: US2004/229925 A1, 2004 ;
Location in patent: Page 3 ;
反应条件
potassium carbonate in water; toluene
Suzuki coupling; 48 h; RefluxInert atmosphere;
参考文献
Kim, Ji-Hoon; Kim, Hee Un; Mi, Dongbo; Jin, Sung-Ho; Shin, Won Suk; Yoon, Sung Cheol; Kang, In-Nam; Hwang, Do-Hoon
Macromolecules, 2012 , vol. 45, # 5 p. 2367 - 2376
反应条件
potassium acetate; palladium diacetate in N,N-dimethyl acetamide
T=130°C; 4 h;
参考文献
ENI S.p.A.; SCHIMPERNA, Giuliana; BIANCHI, Gabriele
Patent: WO2013/21315 A1, 2013 ;
Location in patent: Page/Page column 26-27 ;
反应条件
palladium diacetate; triphenylphosphine in dimethyl sulfoxide
T=145°C; 0.583333 h; Inert atmosphere; Product distribution / selectivity;
参考文献
ENI S.P.A.; SANTARELLI, Samuele; RICCI, Marco; FUSCO, Roberto
Patent: WO2012/7834 A1, 2012 ;
Location in patent: Page/Page column 11; 17-18 ;
反应条件
bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide
T=75°C; 1.5 h;
参考文献
Van Mullekom; Vekemans; Meijer
Chemistry - A European Journal, 1998 , vol. 4, # 7 p. 1235 - 1243
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; copper(I) bromide dimethylsulfide complex; Pd[P(o-tol)3]2; caesium carbonate in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=50°C; Inert atmosphereMolecular sieve;
参考文献
Shimizu, Kenta; Minami, Yasunori; Nakao, Yoshiaki; Ohya, Ken-Ichiro; Ikehira, Hideyuki; Hiyama, Tamejiro
Chemistry Letters, 2013 , vol. 42, # 1 p. 45 - 47
反应条件
1: bromine; hydrogen bromide / 130 °C
2: bis-triphenylphosphine-palladium(II) chloride / tetrahydrofuran / 70 °C / Sonographic reaction
View Scheme
参考文献
Taiwan Textile Research Institute
Patent: EP2333017 A1, 2011 ;
