4,7-二(噻吩-2-基)苯并[c][1,2,5]噻二唑合成路线 （共 14 条）
反应条件
1: thien-2-yl bromide With iodine; magnesium in tetrahydrofuran
Grignard reaction; 2 h; Inert atmosphereReflux;
2: 4,7-dibromobenzo[c][1,2,5]thiadiazole With [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in tetrahydrofuran
T=20°C; Kumada coupling reaction; 22 h; Inert atmosphereReflux;
参考文献
Sun, Xiaobo; Xu, Xinjun; Qiu, Wenfeng; Yu, Gui; Zhang, Hengjun; Gao, Xike; Chen, Shiyan; Song, Yanlin; Liu, Yunqi
Journal of Materials Chemistry, 2008 , vol. 18, # 23 p. 2709 - 2715
反应条件
tetrakis(triphenylphosphine) palladium(0) in toluene
18 h; Reflux;
参考文献
Li, Yilin; Scudiero, Louis; Ren, Tianhui; Dong, Wen-Ji
Journal of Photochemistry and Photobiology A: Chemistry, 2012 , vol. 231, # 1 p. 51 - 59
反应条件
1: thionyl chloride; triethylamine / dichloromethane / Reflux
2: hydrogen bromide; bromine / Reflux
3: bis-triphenylphosphine-palladium(II) chloride / tetrahydrofuran / Reflux
View Scheme
参考文献
Zeng, Shaohang; Yin, Lunxiang; Jiang, Xueying; Li, Yanqin; Li, Kechang
Dyes and Pigments, 2012 , vol. 95, # 2 p. 229 - 235
反应条件
tetrakis(triphenylphosphine) palladium(0); Aliquatreg; 336; potassium carbonate in water; toluene
Suzuki coupling;
参考文献
Lo, Chih-Nan; Hsu, Chain-Shu
Journal of Polymer Science, Part A: Polymer Chemistry, 2011 , vol. 49, # 15 p. 3355 - 3365
